A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

Armağan Atsay; Ilgın Nar; Esin Hamuryudan; Makbule Burkut Koçak; Ahmet Gül

doi:10.1002/slct.201702078

A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

Armağan Atsay^*
, Ilgın Nar
, Esin Hamuryudan
, Makbule Burkut Koçak
, Ahmet Gül

^*Bu çalışma için yazışmadan sorumlu yazar

Istanbul Technical University

Araştırma çıktısı: Dergi yayını › Makale › Hakem

14 Atıf (Scopus)

Özet

Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(α) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(β) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	9233-9235
Sayfa sayısı	3
Dergi	ChemistrySelect
Hacim	2
Basın numarası	28
DOI'lar	https://doi.org/10.1002/slct.201702078
Yayın durumu	Yayınlandı - 29 Eyl 2017

Bibliyografik not

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Finansman

This study was supported by the Research Fund of Istanbul Technical University. AG thanks Turkish Academy of Sciences (TUBA) for partial support.

Finansörler
Istanbul Teknik Üniversitesi

Belgeye Erişim

10.1002/slct.201702078

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine",

abstract = "Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(α) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(β) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.",

keywords = "hexadeca substitution, near-IR, phthalocyanine, self-assembly, supramolecular interactions",

author = "Armağan Atsay and Ilgın Nar and Esin Hamuryudan and Ko{\c c}ak, \{Makbule Burkut\} and Ahmet G{\"u}l",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = sep,

day = "29",

doi = "10.1002/slct.201702078",

language = "English",

volume = "2",

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journal = "ChemistrySelect",

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TY - JOUR

T1 - A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

AU - Atsay, Armağan

AU - Nar, Ilgın

AU - Hamuryudan, Esin

AU - Koçak, Makbule Burkut

AU - Gül, Ahmet

PY - 2017/9/29

Y1 - 2017/9/29

N2 - Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(α) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(β) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.

AB - Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(α) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(β) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.

KW - hexadeca substitution

KW - near-IR

KW - phthalocyanine

KW - self-assembly

KW - supramolecular interactions

UR - https://www.scopus.com/pages/publications/85041831570

U2 - 10.1002/slct.201702078

DO - 10.1002/slct.201702078

M3 - Article

AN - SCOPUS:85041831570

SN - 2365-6549

VL - 2

SP - 9233

EP - 9235

JO - ChemistrySelect

JF - ChemistrySelect

IS - 28

ER -

A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap