A Bifunctional Bulky Thienothiophene Derivative; Synthesis, Electronic-Optical Properties and OLED Applications

Recep Isci; Emine Tekin; Selin P. Mucur; Turan Ozturk

doi:10.1002/slct.202003273

A Bifunctional Bulky Thienothiophene Derivative; Synthesis, Electronic-Optical Properties and OLED Applications

Recep Isci
, Emine Tekin
, Selin P. Mucur
, Turan Ozturk^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

35 Atıf (Scopus)

Özet

Applying thienothiophenes (TT) as a linker, a bulky bifunctional thienothiophene, TT-TPA-TPE3, possessing triphenylamine (TPA) and tetraphenylethylene (TPE) units, was designed, synthesized, and fully characterized. Its optical and electronic properties were explained by UV-Vis spectroscopy, cyclic voltammetry (CV) and Aggregation-Induced Emission (AIE) study. TT-TPA-TPE3 exhibited positive solvatochromism in the range of solvent polarities from DMF to toluene, displaying emissions from yellowish to bluish between 480–525 nm. Utilizing TT-TPA-TPE3 as a hole-transporting layer, its organic light emitting devices (OLEDs) were fabricated and their performances were investigated. The synthesized emitter exhibited green and blue emissions in device applications. A mega Stoke's shift of 114 nm in THF and a large Stoke's shift of 78 nm on ITO were observed. A maximum luminance of 580 cd m⁻² and a turn-on voltage of 7.01 V were obtained, indicating that TT-TPA-TPE3 has a good hole-transporting ability.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	13091-13098
Sayfa sayısı	8
Dergi	ChemistrySelect
Hacim	5
Basın numarası	42
DOI'lar	https://doi.org/10.1002/slct.202003273
Yayın durumu	Yayınlandı - 13 Kas 2020

Bibliyografik not

Publisher Copyright:
© 2020 Wiley-VCH GmbH

Finansman

. We thank Higher Education Council of Turkey (YOK) and TUBITAK grants to Recep Isci (PhD, 100/2000 YOK and 2211A BIDEP/TUBITAK) and Unsped Global Lojistik, Turkey, for financial support. We thank Bariscan Tahaoglu for his help in lab work

Finansörler	Finansör numarası
Higher Education Council of Turkey
YOK	2211A BIDEP/TUBITAK

Belgeye Erişim

10.1002/slct.202003273

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{6d17468f4eb54518a64735e1f6199c11,

title = "A Bifunctional Bulky Thienothiophene Derivative; Synthesis, Electronic-Optical Properties and OLED Applications",

abstract = "Applying thienothiophenes (TT) as a linker, a bulky bifunctional thienothiophene, TT-TPA-TPE3, possessing triphenylamine (TPA) and tetraphenylethylene (TPE) units, was designed, synthesized, and fully characterized. Its optical and electronic properties were explained by UV-Vis spectroscopy, cyclic voltammetry (CV) and Aggregation-Induced Emission (AIE) study. TT-TPA-TPE3 exhibited positive solvatochromism in the range of solvent polarities from DMF to toluene, displaying emissions from yellowish to bluish between 480–525 nm. Utilizing TT-TPA-TPE3 as a hole-transporting layer, its organic light emitting devices (OLEDs) were fabricated and their performances were investigated. The synthesized emitter exhibited green and blue emissions in device applications. A mega Stoke's shift of 114 nm in THF and a large Stoke's shift of 78 nm on ITO were observed. A maximum luminance of 580 cd m−2 and a turn-on voltage of 7.01 V were obtained, indicating that TT-TPA-TPE3 has a good hole-transporting ability.",

keywords = "Bifunctional material, Material science, Organic electronics, Thienothiophenes",

author = "Recep Isci and Emine Tekin and Mucur, \{Selin P.\} and Turan Ozturk",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH GmbH",

year = "2020",

month = nov,

day = "13",

doi = "10.1002/slct.202003273",

language = "English",

volume = "5",

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journal = "ChemistrySelect",

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TY - JOUR

T1 - A Bifunctional Bulky Thienothiophene Derivative; Synthesis, Electronic-Optical Properties and OLED Applications

AU - Isci, Recep

AU - Tekin, Emine

AU - Mucur, Selin P.

AU - Ozturk, Turan

PY - 2020/11/13

Y1 - 2020/11/13

N2 - Applying thienothiophenes (TT) as a linker, a bulky bifunctional thienothiophene, TT-TPA-TPE3, possessing triphenylamine (TPA) and tetraphenylethylene (TPE) units, was designed, synthesized, and fully characterized. Its optical and electronic properties were explained by UV-Vis spectroscopy, cyclic voltammetry (CV) and Aggregation-Induced Emission (AIE) study. TT-TPA-TPE3 exhibited positive solvatochromism in the range of solvent polarities from DMF to toluene, displaying emissions from yellowish to bluish between 480–525 nm. Utilizing TT-TPA-TPE3 as a hole-transporting layer, its organic light emitting devices (OLEDs) were fabricated and their performances were investigated. The synthesized emitter exhibited green and blue emissions in device applications. A mega Stoke's shift of 114 nm in THF and a large Stoke's shift of 78 nm on ITO were observed. A maximum luminance of 580 cd m−2 and a turn-on voltage of 7.01 V were obtained, indicating that TT-TPA-TPE3 has a good hole-transporting ability.

AB - Applying thienothiophenes (TT) as a linker, a bulky bifunctional thienothiophene, TT-TPA-TPE3, possessing triphenylamine (TPA) and tetraphenylethylene (TPE) units, was designed, synthesized, and fully characterized. Its optical and electronic properties were explained by UV-Vis spectroscopy, cyclic voltammetry (CV) and Aggregation-Induced Emission (AIE) study. TT-TPA-TPE3 exhibited positive solvatochromism in the range of solvent polarities from DMF to toluene, displaying emissions from yellowish to bluish between 480–525 nm. Utilizing TT-TPA-TPE3 as a hole-transporting layer, its organic light emitting devices (OLEDs) were fabricated and their performances were investigated. The synthesized emitter exhibited green and blue emissions in device applications. A mega Stoke's shift of 114 nm in THF and a large Stoke's shift of 78 nm on ITO were observed. A maximum luminance of 580 cd m−2 and a turn-on voltage of 7.01 V were obtained, indicating that TT-TPA-TPE3 has a good hole-transporting ability.

KW - Bifunctional material

KW - Material science

KW - Organic electronics

KW - Thienothiophenes

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DO - 10.1002/slct.202003273

M3 - Article

AN - SCOPUS:85096055450

SN - 2365-6549

VL - 5

SP - 13091

EP - 13098

JO - ChemistrySelect

JF - ChemistrySelect

IS - 42

ER -

A Bifunctional Bulky Thienothiophene Derivative; Synthesis, Electronic-Optical Properties and OLED Applications

Özet

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