Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

Kerem Kaya; Mustafa Seba; Takehiro Fujita; Shigeru Yamago; Yusuf Yagci

doi:10.1039/c8py01380b

Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

Kerem Kaya, Mustafa Seba, Takehiro Fujita, Shigeru Yamago^*, Yusuf Yagci

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Organotellurium-mediated polymerization of cyclohexene oxide (CHO), isobutyl vinyl ether (IBVE) and N-vinylcarbazole (NVC) in the presence of diphenyliodonium hexafluorophosphate (DPI) was accomplished under visible light and sunlight. The chain-transfer agent (CTA) ethyl 2-methyl-2-methyltellanylpropionate (EMPTeMe) and poly(methyl methacrylate) with an organotellurium group at the chain end (PMMATeMe) were used as photoinitiators.

Original language	English
Pages (from-to)	5639-5643
Number of pages	5
Journal	Polymer Chemistry
Volume	9
Issue number	48
DOIs	https://doi.org/10.1039/c8py01380b
Publication status	Published - 28 Dec 2018

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© The Royal Society of Chemistry.

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abstract = "Organotellurium-mediated polymerization of cyclohexene oxide (CHO), isobutyl vinyl ether (IBVE) and N-vinylcarbazole (NVC) in the presence of diphenyliodonium hexafluorophosphate (DPI) was accomplished under visible light and sunlight. The chain-transfer agent (CTA) ethyl 2-methyl-2-methyltellanylpropionate (EMPTeMe) and poly(methyl methacrylate) with an organotellurium group at the chain end (PMMATeMe) were used as photoinitiators.",

author = "Kerem Kaya and Mustafa Seba and Takehiro Fujita and Shigeru Yamago and Yusuf Yagci",

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T1 - Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

AU - Kaya, Kerem

AU - Seba, Mustafa

AU - Fujita, Takehiro

AU - Yamago, Shigeru

AU - Yagci, Yusuf

PY - 2018/12/28

Y1 - 2018/12/28

N2 - Organotellurium-mediated polymerization of cyclohexene oxide (CHO), isobutyl vinyl ether (IBVE) and N-vinylcarbazole (NVC) in the presence of diphenyliodonium hexafluorophosphate (DPI) was accomplished under visible light and sunlight. The chain-transfer agent (CTA) ethyl 2-methyl-2-methyltellanylpropionate (EMPTeMe) and poly(methyl methacrylate) with an organotellurium group at the chain end (PMMATeMe) were used as photoinitiators.

AB - Organotellurium-mediated polymerization of cyclohexene oxide (CHO), isobutyl vinyl ether (IBVE) and N-vinylcarbazole (NVC) in the presence of diphenyliodonium hexafluorophosphate (DPI) was accomplished under visible light and sunlight. The chain-transfer agent (CTA) ethyl 2-methyl-2-methyltellanylpropionate (EMPTeMe) and poly(methyl methacrylate) with an organotellurium group at the chain end (PMMATeMe) were used as photoinitiators.

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U2 - 10.1039/c8py01380b

DO - 10.1039/c8py01380b

M3 - Article

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VL - 9

SP - 5639

EP - 5643

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 48

ER -

Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

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