Versatile p(3-sulfopropyl methacrylate) hydrogel reactor for the preparation of Co, Ni nanoparticles and their use in hydrogen production

Tugce Turhan; Yuksel Guvenilir Avcibasi; Nurettin Sahiner

doi:10.1016/j.jiec.2012.12.021

Versatile p(3-sulfopropyl methacrylate) hydrogel reactor for the preparation of Co, Ni nanoparticles and their use in hydrogen production

Tugce Turhan, Yuksel Guvenilir Avcibasi, Nurettin Sahiner^*

^*Corresponding author for this work

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

In this study, polymeric hydrogels derived from 3-sulfopropyl methacrylate (SPM) were used in the preparation of composite-catalyst system in hydrogen generation from hydrolysis of NaBH₄. In order to generate pores and determine their effect on hydrogen production, silica based p(SPM) hydrogels were synthesized also prepared. Additionally, the effects of metal type, temperature, the amount of the catalyst, metal reloading, and reusability were investigated. The activation energy, activation enthalpy, and activation entropy for the hydroylsis reaction of NaBH₄ solution in the presence of p(SPM)-Co catalyst system were calculated as 41.67kJmol^-1, 38.15kJmol^-1, -173.139J/molK, respectively.

Original language	English
Pages (from-to)	1218-1225
Number of pages	8
Journal	Journal of Industrial and Engineering Chemistry
Volume	19
Issue number	4
DOIs	https://doi.org/10.1016/j.jiec.2012.12.021
Publication status	Published - 25 Jul 2013

Funding

This work is supported by the Scientific and Technological Research Council of Turkey (110T649). N. Sahiner is grateful to the Turkish Academy of Science for partial support under 2008 TUBA-GEBIP program.

Funders	Funder number
TUBA-GEBIP
Turkish Academy of Science
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	110T649

Keywords

H production
Hydrogel catalyst
Hydrogel composite reactor
NaBH hydrolysis

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.jiec.2012.12.021

Cite this

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title = "Versatile p(3-sulfopropyl methacrylate) hydrogel reactor for the preparation of Co, Ni nanoparticles and their use in hydrogen production",

abstract = "In this study, polymeric hydrogels derived from 3-sulfopropyl methacrylate (SPM) were used in the preparation of composite-catalyst system in hydrogen generation from hydrolysis of NaBH4. In order to generate pores and determine their effect on hydrogen production, silica based p(SPM) hydrogels were synthesized also prepared. Additionally, the effects of metal type, temperature, the amount of the catalyst, metal reloading, and reusability were investigated. The activation energy, activation enthalpy, and activation entropy for the hydroylsis reaction of NaBH4 solution in the presence of p(SPM)-Co catalyst system were calculated as 41.67kJmol-1, 38.15kJmol-1, -173.139J/molK, respectively.",

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AU - Turhan, Tugce

AU - Avcibasi, Yuksel Guvenilir

AU - Sahiner, Nurettin

PY - 2013/7/25

Y1 - 2013/7/25

N2 - In this study, polymeric hydrogels derived from 3-sulfopropyl methacrylate (SPM) were used in the preparation of composite-catalyst system in hydrogen generation from hydrolysis of NaBH4. In order to generate pores and determine their effect on hydrogen production, silica based p(SPM) hydrogels were synthesized also prepared. Additionally, the effects of metal type, temperature, the amount of the catalyst, metal reloading, and reusability were investigated. The activation energy, activation enthalpy, and activation entropy for the hydroylsis reaction of NaBH4 solution in the presence of p(SPM)-Co catalyst system were calculated as 41.67kJmol-1, 38.15kJmol-1, -173.139J/molK, respectively.

AB - In this study, polymeric hydrogels derived from 3-sulfopropyl methacrylate (SPM) were used in the preparation of composite-catalyst system in hydrogen generation from hydrolysis of NaBH4. In order to generate pores and determine their effect on hydrogen production, silica based p(SPM) hydrogels were synthesized also prepared. Additionally, the effects of metal type, temperature, the amount of the catalyst, metal reloading, and reusability were investigated. The activation energy, activation enthalpy, and activation entropy for the hydroylsis reaction of NaBH4 solution in the presence of p(SPM)-Co catalyst system were calculated as 41.67kJmol-1, 38.15kJmol-1, -173.139J/molK, respectively.

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KW - NaBH hydrolysis

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Versatile p(3-sulfopropyl methacrylate) hydrogel reactor for the preparation of Co, Ni nanoparticles and their use in hydrogen production

Abstract

Funding

Keywords

UN SDGs

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