Ultrasound-assisted rapid one-pot synthesis, characterization and electrical properties of a β-aminoketone with a ferrocenyl moiety

Bahadir Keskin*, S. Arda Öztürkcan, Ahmet Altindal

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The β-aminoketone (4-{[(4-ferrocenyl)(2-oxocyclohexyl)methyl]amino} phenyl)acetonitrile (1), as a new organometallic compound (OMC), has been synthesized and its structure has been characterized by GC-MS, FT-IR, 1H and 13C NMR, and UV-Vis spectral data in detail. The solvatochromic effect with increasing solvent polarity was studied. The voltammetric analyses of the compound showed ferrocene based signals. The electrical transport properties of an Au/OMC/Au device have been investigated. At low voltages, the film showed an ohmic conduction, whereas at higher voltage levels the conduction is dominated by space charged limited conduction (SCLC) with an exponential distribution of trapping levels. From the analysis of the frequency, ω, and dependence of the electrical conductivity, σac, it was observed that the temperature dependence of the frequency exponent, s, and conductivity, σac, were completely in agreement with the prediction of the hopping model.

Original languageEnglish
Pages (from-to)135-140
Number of pages6
JournalPolyhedron
Volume69
DOIs
Publication statusPublished - 17 Feb 2014
Externally publishedYes

Funding

This work was supported by the Research Fund of the Yildiz Technical University . Project No.: 2012-01-02-GEP07.

FundersFunder number
Research Fund of the
Yildiz Technical University

    Keywords

    • Voltammetry
    • ac Conductivity
    • β-Aminoketone

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