Tris (1-chloro-2-propyl) phosphate (TCPP) microcapsules for the preparation of flame-retardant rigid polyurethane foam

Görkem Ülkü; Nesrin Köken; Ahmet Akar; Nilgün Kızılcan; Dilşah Yaman

doi:10.1080/25740881.2020.1850781

Tris (1-chloro-2-propyl) phosphate (TCPP) microcapsules for the preparation of flame-retardant rigid polyurethane foam

Görkem Ülkü, Nesrin Köken^*, Ahmet Akar, Nilgün Kızılcan, Dilşah Yaman

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Toxic liquid tris (1-chloro-2-propyl) phosphate) (TCPP) was microencapsulated with the melamine-formaldehyde resin in water and added as the fire-retardant into the polyurethane foam to slow down its diffusion out. The effect of sodium dodecyl benzenesulfonate and polyvinyl alcohol contents on the particle size was studied and the average size of about 50–250 μm was produced. Increasing the stirring rate and PVA content decreased the diameter of the microcapsule. The cell size of polyurethane foams containing TCPP microcapsules was in the range of 100–600 μm. The polyurethane foam containing 9 wt% of the TCPP microcapsules was HB grade flame-rated.

Original language	English
Pages (from-to)	560-568
Number of pages	9
Journal	Polymer-Plastics Technology and Materials
Volume	60
Issue number	5
DOIs	https://doi.org/10.1080/25740881.2020.1850781
Publication status	Published - 2021

Bibliographical note

Publisher Copyright:
© 2020 Taylor & Francis.

Funding

This work was financial supported by Istanbul Technical University Research Foundation (İTÜ-BAP Project No: TDK-2018-41465).

Funders	Funder number
Istanbul Technical University Research Foundation	TDK-2018-41465

Keywords

fire-retardant
melamine-formaldehyde resin
Microencapsulation
polyurethane foam
tris (1-chloro-2-propyl) phosphate

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10.1080/25740881.2020.1850781

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title = "Tris (1-chloro-2-propyl) phosphate (TCPP) microcapsules for the preparation of flame-retardant rigid polyurethane foam",

abstract = "Toxic liquid tris (1-chloro-2-propyl) phosphate) (TCPP) was microencapsulated with the melamine-formaldehyde resin in water and added as the fire-retardant into the polyurethane foam to slow down its diffusion out. The effect of sodium dodecyl benzenesulfonate and polyvinyl alcohol contents on the particle size was studied and the average size of about 50–250 μm was produced. Increasing the stirring rate and PVA content decreased the diameter of the microcapsule. The cell size of polyurethane foams containing TCPP microcapsules was in the range of 100–600 μm. The polyurethane foam containing 9 wt% of the TCPP microcapsules was HB grade flame-rated.",

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T1 - Tris (1-chloro-2-propyl) phosphate (TCPP) microcapsules for the preparation of flame-retardant rigid polyurethane foam

AU - Ülkü, Görkem

AU - Köken, Nesrin

AU - Akar, Ahmet

AU - Kızılcan, Nilgün

AU - Yaman, Dilşah

PY - 2021

Y1 - 2021

N2 - Toxic liquid tris (1-chloro-2-propyl) phosphate) (TCPP) was microencapsulated with the melamine-formaldehyde resin in water and added as the fire-retardant into the polyurethane foam to slow down its diffusion out. The effect of sodium dodecyl benzenesulfonate and polyvinyl alcohol contents on the particle size was studied and the average size of about 50–250 μm was produced. Increasing the stirring rate and PVA content decreased the diameter of the microcapsule. The cell size of polyurethane foams containing TCPP microcapsules was in the range of 100–600 μm. The polyurethane foam containing 9 wt% of the TCPP microcapsules was HB grade flame-rated.

AB - Toxic liquid tris (1-chloro-2-propyl) phosphate) (TCPP) was microencapsulated with the melamine-formaldehyde resin in water and added as the fire-retardant into the polyurethane foam to slow down its diffusion out. The effect of sodium dodecyl benzenesulfonate and polyvinyl alcohol contents on the particle size was studied and the average size of about 50–250 μm was produced. Increasing the stirring rate and PVA content decreased the diameter of the microcapsule. The cell size of polyurethane foams containing TCPP microcapsules was in the range of 100–600 μm. The polyurethane foam containing 9 wt% of the TCPP microcapsules was HB grade flame-rated.

KW - fire-retardant

KW - melamine-formaldehyde resin

KW - Microencapsulation

KW - polyurethane foam

KW - tris (1-chloro-2-propyl) phosphate

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DO - 10.1080/25740881.2020.1850781

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SN - 2574-0881

VL - 60

SP - 560

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JO - Polymer-Plastics Technology and Materials

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Tris (1-chloro-2-propyl) phosphate (TCPP) microcapsules for the preparation of flame-retardant rigid polyurethane foam

Abstract

Bibliographical note

Funding

Keywords

Access to Document

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