Thermally curable main-chain benzoxazine prepolymers via polycondensation route

Kubra Dogan Demir; Baris Kiskan; Binnur Aydogan; Yusuf Yagci

doi:10.1016/j.reactfunctpolym.2012.04.016

Thermally curable main-chain benzoxazine prepolymers via polycondensation route

Kubra Dogan Demir, Baris Kiskan^*, Binnur Aydogan, Yusuf Yagci

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

98 Citations (Scopus)

Abstract

Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure-property relationships of the cured materials have also been presented and discussed.

Original language	English
Pages (from-to)	346-359
Number of pages	14
Journal	Reactive and Functional Polymers
Volume	73
Issue number	2
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2012.04.016
Publication status	Published - Feb 2013

Keywords

Benzoxazine
Crosslinking
Polybenzoxazine
Polycondensation
Ring opening polymerization
Thermal curing
Thermosetting

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10.1016/j.reactfunctpolym.2012.04.016

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title = "Thermally curable main-chain benzoxazine prepolymers via polycondensation route",

abstract = "Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure-property relationships of the cured materials have also been presented and discussed.",

keywords = "Benzoxazine, Crosslinking, Polybenzoxazine, Polycondensation, Ring opening polymerization, Thermal curing, Thermosetting",

author = "Demir, {Kubra Dogan} and Baris Kiskan and Binnur Aydogan and Yusuf Yagci",

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AU - Demir, Kubra Dogan

AU - Kiskan, Baris

AU - Aydogan, Binnur

AU - Yagci, Yusuf

PY - 2013/2

Y1 - 2013/2

N2 - Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure-property relationships of the cured materials have also been presented and discussed.

AB - Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure-property relationships of the cured materials have also been presented and discussed.

KW - Benzoxazine

KW - Crosslinking

KW - Polybenzoxazine

KW - Polycondensation

KW - Ring opening polymerization

KW - Thermal curing

KW - Thermosetting

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M3 - Article

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EP - 359

JO - Reactive and Functional Polymers

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ER -

Thermally curable main-chain benzoxazine prepolymers via polycondensation route

Abstract

Keywords

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