The Solubilities and Physicochemical Properties of NaH2PO2-NaCl-H2O, NaH2PO2-Zn(H2PO2)2-H2O, and NaCl-Zn(H2PO2)2-H2OTernary Systems and in NaH2PO2-NaCl-Zn(H2PO2)2-H2O Quaternary System at 298.15 K

Sevilay Demirci; Vedat Adlgüzel; Ömer Şahin

doi:10.1021/acs.jced.5b00988

The Solubilities and Physicochemical Properties of NaH₂PO₂-NaCl-H₂O, NaH₂PO₂-Zn(H₂PO₂)₂-H₂O, and NaCl-Zn(H₂PO₂)₂-H₂OTernary Systems and in NaH₂PO₂-NaCl-Zn(H₂PO₂)₂-H₂O Quaternary System at 298.15 K

Sevilay Demirci^*
, Vedat Adlgüzel
, Ömer Şahin

^*Corresponding author for this work

Kafkas University
Siirt University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The physicochemical properties and solubilities of NaH₂PO₂-Zn(H₂PO₂)₂-H₂O, NaH₂PO₂-NaCl-H₂O, and NaCl-Zn(H₂PO₂)₂-H₂O ternary systems and in NaH₂PO₂-NaCl-Zn(H₂PO₂)₂-H₂O quaternary system at 298.15 K were investigated via the isothermal method. Invariant point compositions represent the quaternary system were characterized as the following: 10.65% mass NaCl, 32.51% mass NaH₂PO₂, 6.50% mass Zn(H₂PO₂)₂, and 50.34% mass H₂O. In solid phases, the salts of Zn(H₂PO₂)₂.H₂O, NaCl and NaH₂PO₂·H₂O were recognized. The crystallization area of the salts were obtained as (i) 79.04% Zn(H₂PO₂)₂, (ii) 18.62% NaCl and (iii) 2.34% NaH₂PO₂. Being the least soluble salt, Zn(H₂PO₂)₂ has the largest crystallization area when compared with other salts present in the medium. According to the results, the crystallization area of was the largest in comparison with those of other salts and at the same time it was the least soluble salt.

Original language	English
Pages (from-to)	2292-2298
Number of pages	7
Journal	Journal of Chemical and Engineering Data
Volume	61
Issue number	7
DOIs	https://doi.org/10.1021/acs.jced.5b00988
Publication status	Published - 14 Jul 2016
Externally published	Yes

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© 2016 American Chemical Society.

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10.1021/acs.jced.5b00988

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@article{e47b16c539114dd583edee49eed02faa,

title = "The Solubilities and Physicochemical Properties of NaH2PO2-NaCl-H2O, NaH2PO2-Zn(H2PO2)2-H2O, and NaCl-Zn(H2PO2)2-H2OTernary Systems and in NaH2PO2-NaCl-Zn(H2PO2)2-H2O Quaternary System at 298.15 K",

abstract = "The physicochemical properties and solubilities of NaH2PO2-Zn(H2PO2)2-H2O, NaH2PO2-NaCl-H2O, and NaCl-Zn(H2PO2)2-H2O ternary systems and in NaH2PO2-NaCl-Zn(H2PO2)2-H2O quaternary system at 298.15 K were investigated via the isothermal method. Invariant point compositions represent the quaternary system were characterized as the following: 10.65\% mass NaCl, 32.51\% mass NaH2PO2, 6.50\% mass Zn(H2PO2)2, and 50.34\% mass H2O. In solid phases, the salts of Zn(H2PO2)2.H2O, NaCl and NaH2PO2·H2O were recognized. The crystallization area of the salts were obtained as (i) 79.04\% Zn(H2PO2)2, (ii) 18.62\% NaCl and (iii) 2.34\% NaH2PO2. Being the least soluble salt, Zn(H2PO2)2 has the largest crystallization area when compared with other salts present in the medium. According to the results, the crystallization area of was the largest in comparison with those of other salts and at the same time it was the least soluble salt.",

author = "Sevilay Demirci and Vedat Adlg{\"u}zel and {\"O}mer {\c S}ahin",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = jul,

day = "14",

doi = "10.1021/acs.jced.5b00988",

language = "English",

volume = "61",

pages = "2292--2298",

journal = "Journal of Chemical and Engineering Data",

issn = "0021-9568",

number = "7",

}

The Solubilities and Physicochemical Properties of NaH₂PO₂-NaCl-H₂O, NaH₂PO₂-Zn(H₂PO₂)₂-H₂O, and NaCl-Zn(H₂PO₂)₂-H₂OTernary Systems and in NaH₂PO₂-NaCl-Zn(H₂PO₂)₂-H₂O Quaternary System at 298.15 K. / Demirci, Sevilay; Adlgüzel, Vedat; Şahin, Ömer.
In: Journal of Chemical and Engineering Data, Vol. 61, No. 7, 14.07.2016, p. 2292-2298.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The Solubilities and Physicochemical Properties of NaH2PO2-NaCl-H2O, NaH2PO2-Zn(H2PO2)2-H2O, and NaCl-Zn(H2PO2)2-H2OTernary Systems and in NaH2PO2-NaCl-Zn(H2PO2)2-H2O Quaternary System at 298.15 K

AU - Demirci, Sevilay

AU - Adlgüzel, Vedat

AU - Şahin, Ömer

PY - 2016/7/14

Y1 - 2016/7/14

N2 - The physicochemical properties and solubilities of NaH2PO2-Zn(H2PO2)2-H2O, NaH2PO2-NaCl-H2O, and NaCl-Zn(H2PO2)2-H2O ternary systems and in NaH2PO2-NaCl-Zn(H2PO2)2-H2O quaternary system at 298.15 K were investigated via the isothermal method. Invariant point compositions represent the quaternary system were characterized as the following: 10.65% mass NaCl, 32.51% mass NaH2PO2, 6.50% mass Zn(H2PO2)2, and 50.34% mass H2O. In solid phases, the salts of Zn(H2PO2)2.H2O, NaCl and NaH2PO2·H2O were recognized. The crystallization area of the salts were obtained as (i) 79.04% Zn(H2PO2)2, (ii) 18.62% NaCl and (iii) 2.34% NaH2PO2. Being the least soluble salt, Zn(H2PO2)2 has the largest crystallization area when compared with other salts present in the medium. According to the results, the crystallization area of was the largest in comparison with those of other salts and at the same time it was the least soluble salt.

AB - The physicochemical properties and solubilities of NaH2PO2-Zn(H2PO2)2-H2O, NaH2PO2-NaCl-H2O, and NaCl-Zn(H2PO2)2-H2O ternary systems and in NaH2PO2-NaCl-Zn(H2PO2)2-H2O quaternary system at 298.15 K were investigated via the isothermal method. Invariant point compositions represent the quaternary system were characterized as the following: 10.65% mass NaCl, 32.51% mass NaH2PO2, 6.50% mass Zn(H2PO2)2, and 50.34% mass H2O. In solid phases, the salts of Zn(H2PO2)2.H2O, NaCl and NaH2PO2·H2O were recognized. The crystallization area of the salts were obtained as (i) 79.04% Zn(H2PO2)2, (ii) 18.62% NaCl and (iii) 2.34% NaH2PO2. Being the least soluble salt, Zn(H2PO2)2 has the largest crystallization area when compared with other salts present in the medium. According to the results, the crystallization area of was the largest in comparison with those of other salts and at the same time it was the least soluble salt.

UR - https://www.scopus.com/pages/publications/84978767558

U2 - 10.1021/acs.jced.5b00988

DO - 10.1021/acs.jced.5b00988

M3 - Article

AN - SCOPUS:84978767558

SN - 0021-9568

VL - 61

SP - 2292

EP - 2298

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 7

ER -

The Solubilities and Physicochemical Properties of NaH₂PO₂-NaCl-H₂O, NaH₂PO₂-Zn(H₂PO₂)₂-H₂O, and NaCl-Zn(H₂PO₂)₂-H₂OTernary Systems and in NaH₂PO₂-NaCl-Zn(H₂PO₂)₂-H₂O Quaternary System at 298.15 K

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