The optimization of Cr(VI) reduction and removal by electrocoagulation using response surface methodology

Tugba Ölmez*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

423 Citations (Scopus)

Abstract

In this study Response Surface Methodology (RSM) was employed to investigate the effects of different operating conditions on the removal of hexavalent chromium (Cr(VI)) by the electrocoagulation with stainless steel electrodes. Central Composite Design (CCD) was used for the optimization of the electrocoagulation process and to evaluate the effects and interactions of process variables: applied electric current, electrolyte concentration and application time on the removal of Cr(VI). A sample of metal finishing industry wastewater having a high Cr(VI) concentration of 1470 mg/L was used in the experimental study. The optimum conditions for complete (100%) Cr(VI) removal were established as 7.4 A applied electric current, 33.6 mM electrolyte (NaCl) concentration and 70 min application time. The amount of sludge produced under the conditions optimized based on the results from the model was lower than the amount generated by chemical treatment with FeSO4·7H2O and non-hazardous in nature.

Original languageEnglish
Pages (from-to)1371-1378
Number of pages8
JournalJournal of Hazardous Materials
Volume162
Issue number2-3
DOIs
Publication statusPublished - 15 Mar 2009

Keywords

  • Chemical sludge generation
  • Cr(VI) reduction and removal
  • Electrocoagulation process
  • Metal finishing industry wastewater
  • Response Surface Methodology

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