The manufacture of organic carbonate-poly(methyl ethylacrylate) nanowebs with thermal buffering effect

Emel Onder; Nihal Sarier; Refik Arat

doi:10.1016/j.tca.2017.10.003

The manufacture of organic carbonate-poly(methyl ethylacrylate) nanowebs with thermal buffering effect

Emel Onder, Nihal Sarier^*, Refik Arat

^*Corresponding author for this work

Department of Textile Engineering

Istanbul Kultur University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

In this study, novel nanowebs provided with thermal buffering properties were developed via coaxial electrospinning. Environmental friendly and nontoxic dialkyl and dialkenyl carbonates (DACs), namely, didecyl carbonate, didodecyl carbonate, ditetradecyl carbonate, dihexadecyl carbonate, dioctadecyl carbonate and dioleyl carbonate were synthesized from their fatty alcohols based on carbonate interchange reaction. Then the DAC-PMEA nanowebs were produced using 10–50 w% DAC in 3:1 chloroform-ethanol solution as core and 15 w% poly(methyl ethylacrylate) (PMEA)in ethanol as shell by coaxial electrospinning. The SEM images of the nanowebs presented randomly oriented, ultrafine fibers identified with smooth surfaces, continuous and cylindrical shapes. The nanowebs were able to provide considerable enthalpies (40–100 J g⁻¹) during their repeated phase changes, up to hundred heating-cooling cycles, corresponding to 52–92% efficiencies obtained from electrospinning. These shape stabilized, lightweight DAC-PMEA nanowebs showed a significant potential for the dynamic thermal insulation applications across various industries, especially for the protection of temperature sensitive materials.

Original language	English
Pages (from-to)	170-184
Number of pages	15
Journal	Thermochimica Acta
Volume	657
DOIs	https://doi.org/10.1016/j.tca.2017.10.003
Publication status	Published - 10 Nov 2017

Bibliographical note

Publisher Copyright:
© 2017 Elsevier B.V.

Funding

We would like to thank The Scientific & Technical Research Council of Turkey (TUBITAK) for the financial support of this study (project code: TUBITAK 213M281). We acknowledge Istanbul Kultur University for their financial support. We are also thankful to Evonik Company (USA) for supplying Eudragit L100-55 copolymer.

Funders	Funder number
Istanbul Kultur University
Scientific & Technical Research Council of Turkey
TUBITAK	213M281

Keywords

Coaxial electrospinning
Nanoweb
Organic carbonate
Phase change material
Thermal properties

Access to Document

10.1016/j.tca.2017.10.003

Cite this

@article{594e7cd889ba4c459b5a56357e647e87,

title = "The manufacture of organic carbonate-poly(methyl ethylacrylate) nanowebs with thermal buffering effect",

abstract = "In this study, novel nanowebs provided with thermal buffering properties were developed via coaxial electrospinning. Environmental friendly and nontoxic dialkyl and dialkenyl carbonates (DACs), namely, didecyl carbonate, didodecyl carbonate, ditetradecyl carbonate, dihexadecyl carbonate, dioctadecyl carbonate and dioleyl carbonate were synthesized from their fatty alcohols based on carbonate interchange reaction. Then the DAC-PMEA nanowebs were produced using 10–50 w% DAC in 3:1 chloroform-ethanol solution as core and 15 w% poly(methyl ethylacrylate) (PMEA)in ethanol as shell by coaxial electrospinning. The SEM images of the nanowebs presented randomly oriented, ultrafine fibers identified with smooth surfaces, continuous and cylindrical shapes. The nanowebs were able to provide considerable enthalpies (40–100 J g−1) during their repeated phase changes, up to hundred heating-cooling cycles, corresponding to 52–92% efficiencies obtained from electrospinning. These shape stabilized, lightweight DAC-PMEA nanowebs showed a significant potential for the dynamic thermal insulation applications across various industries, especially for the protection of temperature sensitive materials.",

keywords = "Coaxial electrospinning, Nanoweb, Organic carbonate, Phase change material, Thermal properties",

author = "Emel Onder and Nihal Sarier and Refik Arat",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = nov,

day = "10",

doi = "10.1016/j.tca.2017.10.003",

language = "English",

volume = "657",

pages = "170--184",

journal = "Thermochimica Acta",

issn = "0040-6031",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - The manufacture of organic carbonate-poly(methyl ethylacrylate) nanowebs with thermal buffering effect

AU - Onder, Emel

AU - Sarier, Nihal

AU - Arat, Refik

PY - 2017/11/10

Y1 - 2017/11/10

N2 - In this study, novel nanowebs provided with thermal buffering properties were developed via coaxial electrospinning. Environmental friendly and nontoxic dialkyl and dialkenyl carbonates (DACs), namely, didecyl carbonate, didodecyl carbonate, ditetradecyl carbonate, dihexadecyl carbonate, dioctadecyl carbonate and dioleyl carbonate were synthesized from their fatty alcohols based on carbonate interchange reaction. Then the DAC-PMEA nanowebs were produced using 10–50 w% DAC in 3:1 chloroform-ethanol solution as core and 15 w% poly(methyl ethylacrylate) (PMEA)in ethanol as shell by coaxial electrospinning. The SEM images of the nanowebs presented randomly oriented, ultrafine fibers identified with smooth surfaces, continuous and cylindrical shapes. The nanowebs were able to provide considerable enthalpies (40–100 J g−1) during their repeated phase changes, up to hundred heating-cooling cycles, corresponding to 52–92% efficiencies obtained from electrospinning. These shape stabilized, lightweight DAC-PMEA nanowebs showed a significant potential for the dynamic thermal insulation applications across various industries, especially for the protection of temperature sensitive materials.

AB - In this study, novel nanowebs provided with thermal buffering properties were developed via coaxial electrospinning. Environmental friendly and nontoxic dialkyl and dialkenyl carbonates (DACs), namely, didecyl carbonate, didodecyl carbonate, ditetradecyl carbonate, dihexadecyl carbonate, dioctadecyl carbonate and dioleyl carbonate were synthesized from their fatty alcohols based on carbonate interchange reaction. Then the DAC-PMEA nanowebs were produced using 10–50 w% DAC in 3:1 chloroform-ethanol solution as core and 15 w% poly(methyl ethylacrylate) (PMEA)in ethanol as shell by coaxial electrospinning. The SEM images of the nanowebs presented randomly oriented, ultrafine fibers identified with smooth surfaces, continuous and cylindrical shapes. The nanowebs were able to provide considerable enthalpies (40–100 J g−1) during their repeated phase changes, up to hundred heating-cooling cycles, corresponding to 52–92% efficiencies obtained from electrospinning. These shape stabilized, lightweight DAC-PMEA nanowebs showed a significant potential for the dynamic thermal insulation applications across various industries, especially for the protection of temperature sensitive materials.

KW - Coaxial electrospinning

KW - Nanoweb

KW - Organic carbonate

KW - Phase change material

KW - Thermal properties

UR - http://www.scopus.com/inward/record.url?scp=85030843665&partnerID=8YFLogxK

U2 - 10.1016/j.tca.2017.10.003

DO - 10.1016/j.tca.2017.10.003

M3 - Article

AN - SCOPUS:85030843665

SN - 0040-6031

VL - 657

SP - 170

EP - 184

JO - Thermochimica Acta

JF - Thermochimica Acta

ER -

The manufacture of organic carbonate-poly(methyl ethylacrylate) nanowebs with thermal buffering effect

Abstract

Bibliographical note

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this