The free‐radical polymerization of acrylamide initiated with ceric sulfate in the presence of amino acids

Candan Erbil; A. Bahattin Soydan; A. Zehra Aroǧuz; A. Sezai Saraç

doi:10.1002/apmc.1993.052130107

The free‐radical polymerization of acrylamide initiated with ceric sulfate in the presence of amino acids

Candan Erbil^*, A. Bahattin Soydan, A. Zehra Aroǧuz, A. Sezai Saraç

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Polymerization of acrylamide initiated with ceric (IV) ion in the presence of methionine, phenylalanine, serine and aspartic acid was investigated in sulfuric acid solution. Maximum yield was obtained at 70°C and sulfuric acid concentration of 0.16 mol/1. Both conductometric titration and FT‐IR results showed that the resulting polymers contained carboxy end groups. According to these findings and previous studies in this field, a suitable polymerization mechanism was proposed.

Original language	English
Pages (from-to)	55-63
Number of pages	9
Journal	Macromolecular Materials and Engineering
Volume	213
Issue number	1
DOIs	https://doi.org/10.1002/apmc.1993.052130107
Publication status	Published - Dec 1993

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abstract = "Polymerization of acrylamide initiated with ceric (IV) ion in the presence of methionine, phenylalanine, serine and aspartic acid was investigated in sulfuric acid solution. Maximum yield was obtained at 70°C and sulfuric acid concentration of 0.16 mol/1. Both conductometric titration and FT‐IR results showed that the resulting polymers contained carboxy end groups. According to these findings and previous studies in this field, a suitable polymerization mechanism was proposed.",

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AB - Polymerization of acrylamide initiated with ceric (IV) ion in the presence of methionine, phenylalanine, serine and aspartic acid was investigated in sulfuric acid solution. Maximum yield was obtained at 70°C and sulfuric acid concentration of 0.16 mol/1. Both conductometric titration and FT‐IR results showed that the resulting polymers contained carboxy end groups. According to these findings and previous studies in this field, a suitable polymerization mechanism was proposed.

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The free‐radical polymerization of acrylamide initiated with ceric sulfate in the presence of amino acids

Abstract

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