The electrocatalytic properties of palladium electrodes for the oxidation of d-glucose in alkaline medium

I. Becerik; F. Kadirgan

doi:10.1016/0013-4686(92)87065-8

The electrocatalytic properties of palladium electrodes for the oxidation of d-glucose in alkaline medium

I. Becerik, F. Kadirgan^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

The electrooxidation of glucose on smooth Pd in alkaline medium has been studied by electrochemical and polarimetric techniques. During the polarimetric experiments evolution of the specific rotation angle is investigated as a function of time, OH^- concentration and the temperature. In order to determine the kinetic parameters (effect of sweep rate, effect of temperature, order of reaction, etc.), an electrochemical systematic study is realised. Reaction mechanisms are suggested which take into account these results.

Original language	English
Pages (from-to)	2651-2657
Number of pages	7
Journal	Electrochimica Acta
Volume	37
Issue number	14
DOIs	https://doi.org/10.1016/0013-4686(92)87065-8
Publication status	Published - Nov 1992

Keywords

d-glucose
electro-oxidation
electrocatalysis
electrolysis
palladium electrode
polarimetric experiments

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10.1016/0013-4686(92)87065-8

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abstract = "The electrooxidation of glucose on smooth Pd in alkaline medium has been studied by electrochemical and polarimetric techniques. During the polarimetric experiments evolution of the specific rotation angle is investigated as a function of time, OH- concentration and the temperature. In order to determine the kinetic parameters (effect of sweep rate, effect of temperature, order of reaction, etc.), an electrochemical systematic study is realised. Reaction mechanisms are suggested which take into account these results.",

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AB - The electrooxidation of glucose on smooth Pd in alkaline medium has been studied by electrochemical and polarimetric techniques. During the polarimetric experiments evolution of the specific rotation angle is investigated as a function of time, OH- concentration and the temperature. In order to determine the kinetic parameters (effect of sweep rate, effect of temperature, order of reaction, etc.), an electrochemical systematic study is realised. Reaction mechanisms are suggested which take into account these results.

KW - d-glucose

KW - electro-oxidation

KW - electrocatalysis

KW - electrolysis

KW - palladium electrode

KW - polarimetric experiments

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ER -

The electrocatalytic properties of palladium electrodes for the oxidation of d-glucose in alkaline medium

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Keywords

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