The effect of neutralizing agent on the synthesis and characterization of Mn                         3                         O                         4                          nanoparticles

Z. Durmus; M. Tomas; A. Baykal; H. Kavas; T. Gürkaynak Altınçekiç; M. S. Toprak

doi:10.1134/S0036023610120211

The effect of neutralizing agent on the synthesis and characterization of Mn ₃ O ₄ nanoparticles

Z. Durmus, M. Tomas, A. Baykal^*, H. Kavas, T. Gürkaynak Altınçekiç, M. S. Toprak

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

We report on the synthesis of Mn ₃ O ₄ nanoparticles via a two-step hydrothermal route by using Mn(CH ₃ COO) ₂ as the only starting material and TMAOH and NaOH as hydrolysing agents. XRD and FT-IR analyses confirmed the composition and structure of Mn ₃ O ₄ . TEM images showed that spheroid Mn ₃ O ₄ nanostructures obtained by this method have average particle size of 6 and 14 nm for NaOH and TMAOH hydrolyzed samples respectively. Particle size analysis indicated a strong aggregation of nanoparticles and exhibited bi-modal distribution with average size of aggregates as ̃250 nm and 1.1 μm for both samples. Zeta potential analysis revealed adsorbed TMAOH species on the surface of Mn ₃ O ₄ nanoparticles hydrolyzed using TMAOH. ESR analyses resulted in broader lines and smaller g values than bulk Mn ₃ O ₄ nanoparticles, probably due to the exchange-coupled system with unlike spins such as canted spin at surface of high-surface-disordered nanoparticles.

Original language	English
Pages (from-to)	1947-1952
Number of pages	6
Journal	Russian Journal of Inorganic Chemistry
Volume	55
Issue number	12
DOIs	https://doi.org/10.1134/S0036023610120211
Publication status	Published - Dec 2010
Externally published	Yes

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Durmus, Z., Tomas, M., Baykal, A., Kavas, H., Gürkaynak Altınçekiç, T., & Toprak, M. S. (2010). The effect of neutralizing agent on the synthesis and characterization of Mn ₃ O ₄ nanoparticles Russian Journal of Inorganic Chemistry, 55(12), 1947-1952. https://doi.org/10.1134/S0036023610120211

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title = " The effect of neutralizing agent on the synthesis and characterization of Mn 3 O 4 nanoparticles ",

abstract = " We report on the synthesis of Mn 3 O 4 nanoparticles via a two-step hydrothermal route by using Mn(CH 3 COO) 2 as the only starting material and TMAOH and NaOH as hydrolysing agents. XRD and FT-IR analyses confirmed the composition and structure of Mn 3 O 4 . TEM images showed that spheroid Mn 3 O 4 nanostructures obtained by this method have average particle size of 6 and 14 nm for NaOH and TMAOH hydrolyzed samples respectively. Particle size analysis indicated a strong aggregation of nanoparticles and exhibited bi-modal distribution with average size of aggregates as{\~ }250 nm and 1.1 μm for both samples. Zeta potential analysis revealed adsorbed TMAOH species on the surface of Mn 3 O 4 nanoparticles hydrolyzed using TMAOH. ESR analyses resulted in broader lines and smaller g values than bulk Mn 3 O 4 nanoparticles, probably due to the exchange-coupled system with unlike spins such as canted spin at surface of high-surface-disordered nanoparticles.",

author = "Z. Durmus and M. Tomas and A. Baykal and H. Kavas and \{G{\"u}rkaynak Altın{\c c}eki{\c c}\}, T. and Toprak, \{M. S.\}",

year = "2010",

month = dec,

doi = "10.1134/S0036023610120211",

language = "English",

volume = "55",

pages = "1947--1952",

journal = "Russian Journal of Inorganic Chemistry",

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publisher = "Pleiades Publishing",

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Durmus, Z, Tomas, M, Baykal, A, Kavas, H, Gürkaynak Altınçekiç, T & Toprak, MS 2010, ' The effect of neutralizing agent on the synthesis and characterization of Mn ₃ O ₄ nanoparticles ', Russian Journal of Inorganic Chemistry, vol. 55, no. 12, pp. 1947-1952. https://doi.org/10.1134/S0036023610120211

The effect of neutralizing agent on the synthesis and characterization of Mn ₃ O ₄ nanoparticles . / Durmus, Z.; Tomas, M.; Baykal, A. et al.
In: Russian Journal of Inorganic Chemistry, Vol. 55, No. 12, 12.2010, p. 1947-1952.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The effect of neutralizing agent on the synthesis and characterization of Mn 3 O 4 nanoparticles

AU - Durmus, Z.

AU - Tomas, M.

AU - Baykal, A.

AU - Kavas, H.

AU - Gürkaynak Altınçekiç, T.

AU - Toprak, M. S.

PY - 2010/12

Y1 - 2010/12

N2 - We report on the synthesis of Mn 3 O 4 nanoparticles via a two-step hydrothermal route by using Mn(CH 3 COO) 2 as the only starting material and TMAOH and NaOH as hydrolysing agents. XRD and FT-IR analyses confirmed the composition and structure of Mn 3 O 4 . TEM images showed that spheroid Mn 3 O 4 nanostructures obtained by this method have average particle size of 6 and 14 nm for NaOH and TMAOH hydrolyzed samples respectively. Particle size analysis indicated a strong aggregation of nanoparticles and exhibited bi-modal distribution with average size of aggregates as ̃250 nm and 1.1 μm for both samples. Zeta potential analysis revealed adsorbed TMAOH species on the surface of Mn 3 O 4 nanoparticles hydrolyzed using TMAOH. ESR analyses resulted in broader lines and smaller g values than bulk Mn 3 O 4 nanoparticles, probably due to the exchange-coupled system with unlike spins such as canted spin at surface of high-surface-disordered nanoparticles.

AB - We report on the synthesis of Mn 3 O 4 nanoparticles via a two-step hydrothermal route by using Mn(CH 3 COO) 2 as the only starting material and TMAOH and NaOH as hydrolysing agents. XRD and FT-IR analyses confirmed the composition and structure of Mn 3 O 4 . TEM images showed that spheroid Mn 3 O 4 nanostructures obtained by this method have average particle size of 6 and 14 nm for NaOH and TMAOH hydrolyzed samples respectively. Particle size analysis indicated a strong aggregation of nanoparticles and exhibited bi-modal distribution with average size of aggregates as ̃250 nm and 1.1 μm for both samples. Zeta potential analysis revealed adsorbed TMAOH species on the surface of Mn 3 O 4 nanoparticles hydrolyzed using TMAOH. ESR analyses resulted in broader lines and smaller g values than bulk Mn 3 O 4 nanoparticles, probably due to the exchange-coupled system with unlike spins such as canted spin at surface of high-surface-disordered nanoparticles.

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M3 - Article

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SN - 0036-0236

VL - 55

SP - 1947

EP - 1952

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

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ER -

Durmus Z, Tomas M, Baykal A, Kavas H, Gürkaynak Altınçekiç T, Toprak MS. The effect of neutralizing agent on the synthesis and characterization of Mn ₃ O ₄ nanoparticles Russian Journal of Inorganic Chemistry. 2010 Dec;55(12):1947-1952. doi: 10.1134/S0036023610120211

The effect of neutralizing agent on the synthesis and characterization of Mn ₃ O ₄ nanoparticles

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