Abstract
The effects of heat-treatment on α → β sialon transformation in dense, agglomerate-free Ln-sialon/ SiCp(Ln=Nd, Yb) composites are reported. The stability of the α-sialon phase is not only dependent on the temperature and time of heat-treatment, but also on the kind of additive and the amount of SiC particles. In Nd-densified samples, the a-sialon phase is very unstable at 1450°C and transforms almost totally to the β phase with the Nd-M (melilite) phase and NdAlO3 as grain-boundary crystalline phases. In contrast, Yb3+-densified samples show good stability for the a-sialon phase at 1450°C, with only a small amount of β-sialon produced. The crystalline grain-boundary phases produced in this case are Yb-garnet, and Yb-J-phase.
| Original language | English |
|---|---|
| Pages (from-to) | 587-592 |
| Number of pages | 6 |
| Journal | Journal of the European Ceramic Society |
| Volume | 17 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Feb 1997 |
| Externally published | Yes |
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