Test of Halperin-Lubensky-Ma crossover function at the N- Sm-A transition in liquid crystal binary mixtures via high-resolution birefringence measurements

We report optical birefringence data for a series of mixtures of the liquid crystals octylcyanobiphenyl (8CB) and decylcyanobiphenyl (10CB). Nematic order parameter S data in the nematic and smectic A phases have been derived from phase angle changes obtained in temperature scans with a rotating analyzer method. These S values have been used to arrive at values for possible entropy discontinuities at the smectic A to nematic phase transition temperature TNA. The 10CB mole fraction dependence of the obtained entropy discontinuities could be well fitted with a crossover function consistent with the mean-field free-energy expression with a nonzero cubic term arising from the coupling between the smectic-A order parameter and the orientational order parameter director fluctuations in the Halperin-Lubensky-Ma theory. The obtained results are in good agreement with existing results from adiabatic scanning calorimetry. By exploiting the fact that the temperature derivative of the order parameter S(T) near TNA exhibits the same power law divergence as the specific heat capacity, we have extracted the effective critical exponent α values for the compositions under study. The critical exponent α has been observed to reach the tricritical value αTCP=0.5 for the 10CB mole fraction of x=0.330.