Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes

Mustafa Dolaz; Vickie McKee; Ayşegül Gölcü; Mehmet Tümer

doi:10.1016/j.saa.2008.06.012

Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes

Mustafa Dolaz, Vickie McKee, Ayşegül Gölcü, Mehmet Tümer^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

In this study, N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine (L) and its Cu(II), Co(II) and Ni(II) complexes were prepared and characterized by the analytical and spectroscopic methods. The analytical data show the composition of the metal complex to be [M₂L(Cl)₄(H₂O)₂], where L is the Schiff base ligand. The conductance data indicate that all the complexes are non-electrolytes. The compound (L) behaves as a monodentate ligand. But, obtained complexes have binuclear nature. The electrochemical properties of the metal complexes are dependent on reversible, irreversible and quasi-reversible redox waves in the anodic and cathodic regions due to oxidation and reduction of the metal ions. The single crystal of the ligand (L) was obtained from CH₃CN solution. Space group and crystal system of the ligand are P2₁/C and monoclinic, respectively.

Original language	English
Pages (from-to)	1648-1654
Number of pages	7
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	71
Issue number	5
DOIs	https://doi.org/10.1016/j.saa.2008.06.012
Publication status	Published - Jan 2009
Externally published	Yes

Keywords

Electrochemical
Reversible
Schiff base
X-ray

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Dolaz, M., McKee, V., Gölcü, A., & Tümer, M. (2009). Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 71(5), 1648-1654. https://doi.org/10.1016/j.saa.2008.06.012

Dolaz, Mustafa ; McKee, Vickie ; Gölcü, Ayşegül et al. / Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes. In: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2009 ; Vol. 71, No. 5. pp. 1648-1654.

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title = "Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes",

abstract = "In this study, N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine (L) and its Cu(II), Co(II) and Ni(II) complexes were prepared and characterized by the analytical and spectroscopic methods. The analytical data show the composition of the metal complex to be [M2L(Cl)4(H2O)2], where L is the Schiff base ligand. The conductance data indicate that all the complexes are non-electrolytes. The compound (L) behaves as a monodentate ligand. But, obtained complexes have binuclear nature. The electrochemical properties of the metal complexes are dependent on reversible, irreversible and quasi-reversible redox waves in the anodic and cathodic regions due to oxidation and reduction of the metal ions. The single crystal of the ligand (L) was obtained from CH3CN solution. Space group and crystal system of the ligand are P21/C and monoclinic, respectively.",

keywords = "Electrochemical, Reversible, Schiff base, X-ray",

author = "Mustafa Dolaz and Vickie McKee and Ay{\c s}eg{\"u}l G{\"o}lc{\"u} and Mehmet T{\"u}mer",

year = "2009",

month = jan,

doi = "10.1016/j.saa.2008.06.012",

language = "English",

volume = "71",

pages = "1648--1654",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

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Dolaz, M, McKee, V, Gölcü, A & Tümer, M 2009, 'Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes', Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, vol. 71, no. 5, pp. 1648-1654. https://doi.org/10.1016/j.saa.2008.06.012

Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes. / Dolaz, Mustafa; McKee, Vickie; Gölcü, Ayşegül et al.
In: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Vol. 71, No. 5, 01.2009, p. 1648-1654.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes

AU - Dolaz, Mustafa

AU - McKee, Vickie

AU - Gölcü, Ayşegül

AU - Tümer, Mehmet

PY - 2009/1

Y1 - 2009/1

N2 - In this study, N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine (L) and its Cu(II), Co(II) and Ni(II) complexes were prepared and characterized by the analytical and spectroscopic methods. The analytical data show the composition of the metal complex to be [M2L(Cl)4(H2O)2], where L is the Schiff base ligand. The conductance data indicate that all the complexes are non-electrolytes. The compound (L) behaves as a monodentate ligand. But, obtained complexes have binuclear nature. The electrochemical properties of the metal complexes are dependent on reversible, irreversible and quasi-reversible redox waves in the anodic and cathodic regions due to oxidation and reduction of the metal ions. The single crystal of the ligand (L) was obtained from CH3CN solution. Space group and crystal system of the ligand are P21/C and monoclinic, respectively.

AB - In this study, N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine (L) and its Cu(II), Co(II) and Ni(II) complexes were prepared and characterized by the analytical and spectroscopic methods. The analytical data show the composition of the metal complex to be [M2L(Cl)4(H2O)2], where L is the Schiff base ligand. The conductance data indicate that all the complexes are non-electrolytes. The compound (L) behaves as a monodentate ligand. But, obtained complexes have binuclear nature. The electrochemical properties of the metal complexes are dependent on reversible, irreversible and quasi-reversible redox waves in the anodic and cathodic regions due to oxidation and reduction of the metal ions. The single crystal of the ligand (L) was obtained from CH3CN solution. Space group and crystal system of the ligand are P21/C and monoclinic, respectively.

KW - Electrochemical

KW - Reversible

KW - Schiff base

KW - X-ray

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DO - 10.1016/j.saa.2008.06.012

M3 - Article

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AN - SCOPUS:56049121910

SN - 1386-1425

VL - 71

SP - 1648

EP - 1654

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

IS - 5

ER -

Synthesis, structural characterization, thermal and electrochemical studies of the N,N′-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes

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Keywords

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