Synthesis of unsymmetrical carboxyphthalocyanines by palladium-catalyzed hydroxycarbonylation of iodo-substituted precursors

Íñigo Aguirre De Carcer García; Altug Mert Sevim; Andrés De La Escosura; Tomás Torres

doi:10.1039/c3ob27468c

Synthesis of unsymmetrical carboxyphthalocyanines by palladium-catalyzed hydroxycarbonylation of iodo-substituted precursors

Íñigo Aguirre De Carcer García, Altug Mert Sevim, Andrés De La Escosura, Tomás Torres^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Phthalocyanines (Pcs) containing a carboxylic acid functionality directly bound to the macrocycle have been synthesized, in one step and in good yields, from iodo-substituted Pc precursors. This methodology represents a convenient alternative to the commonly used method based on two consecutive oxidations of hydroxymethyl Pcs.

Original language	English
Pages (from-to)	2237-2240
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	11
Issue number	14
DOIs	https://doi.org/10.1039/c3ob27468c
Publication status	Published - 14 Apr 2013
Externally published	Yes

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10.1039/c3ob27468c

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title = "Synthesis of unsymmetrical carboxyphthalocyanines by palladium-catalyzed hydroxycarbonylation of iodo-substituted precursors",

abstract = "Phthalocyanines (Pcs) containing a carboxylic acid functionality directly bound to the macrocycle have been synthesized, in one step and in good yields, from iodo-substituted Pc precursors. This methodology represents a convenient alternative to the commonly used method based on two consecutive oxidations of hydroxymethyl Pcs.",

author = "{Aguirre De Carcer Garc{\'i}a}, {\'I}{\~n}igo and Sevim, {Altug Mert} and {De La Escosura}, Andr{\'e}s and Tom{\'a}s Torres",

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AU - Aguirre De Carcer García, Íñigo

AU - Sevim, Altug Mert

AU - De La Escosura, Andrés

AU - Torres, Tomás

PY - 2013/4/14

Y1 - 2013/4/14

N2 - Phthalocyanines (Pcs) containing a carboxylic acid functionality directly bound to the macrocycle have been synthesized, in one step and in good yields, from iodo-substituted Pc precursors. This methodology represents a convenient alternative to the commonly used method based on two consecutive oxidations of hydroxymethyl Pcs.

AB - Phthalocyanines (Pcs) containing a carboxylic acid functionality directly bound to the macrocycle have been synthesized, in one step and in good yields, from iodo-substituted Pc precursors. This methodology represents a convenient alternative to the commonly used method based on two consecutive oxidations of hydroxymethyl Pcs.

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U2 - 10.1039/c3ob27468c

DO - 10.1039/c3ob27468c

M3 - Article

AN - SCOPUS:84875016319

SN - 1477-0520

VL - 11

SP - 2237

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JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 14

ER -

Synthesis of unsymmetrical carboxyphthalocyanines by palladium-catalyzed hydroxycarbonylation of iodo-substituted precursors

Abstract

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