Synthesis of triglyceride-based urethane macromers and their use in copolymerization

Alev Koprululu; Aysen Onen; I. Ersin Serhatli; F. Seniha Guner

doi:10.1016/j.porgcoat.2008.06.006

Synthesis of triglyceride-based urethane macromers and their use in copolymerization

Alev Koprululu, Aysen Onen, I. Ersin Serhatli, F. Seniha Guner^*

^*Corresponding author for this work

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Triglyceride oil-based urethane macromer (TGU) containing vinyl double bond was synthesized by the reaction of partial glyceride mixture (PGM) and methyl vinyl isocyanate (MVI). Free radical polymerization and copolymerization of TGU was studied. The structure of the TGU and polymers were elucidated by gel permeation chromatography (GPC) analysis, Fourier transform infrared spectroscopy (FT-IR) and ¹H nuclear magnetic resonance (¹H NMR) spectral measurements. The film properties of polymers were investigated by water resistance, alkali and acid resistance and contact angle measurements.

Original language	English
Pages (from-to)	365-371
Number of pages	7
Journal	Progress in Organic Coatings
Volume	63
Issue number	4
DOIs	https://doi.org/10.1016/j.porgcoat.2008.06.006
Publication status	Published - Nov 2008

Funding

The financial support of ITU Research Fund is gratefully acknowledged.

Funders	Funder number
ITU Research Fund

Keywords

Macromer
Triglyceride oil
Urethane

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10.1016/j.porgcoat.2008.06.006

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title = "Synthesis of triglyceride-based urethane macromers and their use in copolymerization",

abstract = "Triglyceride oil-based urethane macromer (TGU) containing vinyl double bond was synthesized by the reaction of partial glyceride mixture (PGM) and methyl vinyl isocyanate (MVI). Free radical polymerization and copolymerization of TGU was studied. The structure of the TGU and polymers were elucidated by gel permeation chromatography (GPC) analysis, Fourier transform infrared spectroscopy (FT-IR) and 1H nuclear magnetic resonance (1H NMR) spectral measurements. The film properties of polymers were investigated by water resistance, alkali and acid resistance and contact angle measurements.",

keywords = "Macromer, Triglyceride oil, Urethane",

author = "Alev Koprululu and Aysen Onen and Serhatli, {I. Ersin} and Guner, {F. Seniha}",

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T1 - Synthesis of triglyceride-based urethane macromers and their use in copolymerization

AU - Koprululu, Alev

AU - Onen, Aysen

AU - Serhatli, I. Ersin

AU - Guner, F. Seniha

PY - 2008/11

Y1 - 2008/11

N2 - Triglyceride oil-based urethane macromer (TGU) containing vinyl double bond was synthesized by the reaction of partial glyceride mixture (PGM) and methyl vinyl isocyanate (MVI). Free radical polymerization and copolymerization of TGU was studied. The structure of the TGU and polymers were elucidated by gel permeation chromatography (GPC) analysis, Fourier transform infrared spectroscopy (FT-IR) and 1H nuclear magnetic resonance (1H NMR) spectral measurements. The film properties of polymers were investigated by water resistance, alkali and acid resistance and contact angle measurements.

AB - Triglyceride oil-based urethane macromer (TGU) containing vinyl double bond was synthesized by the reaction of partial glyceride mixture (PGM) and methyl vinyl isocyanate (MVI). Free radical polymerization and copolymerization of TGU was studied. The structure of the TGU and polymers were elucidated by gel permeation chromatography (GPC) analysis, Fourier transform infrared spectroscopy (FT-IR) and 1H nuclear magnetic resonance (1H NMR) spectral measurements. The film properties of polymers were investigated by water resistance, alkali and acid resistance and contact angle measurements.

KW - Macromer

KW - Triglyceride oil

KW - Urethane

UR - http://www.scopus.com/inward/record.url?scp=55049092981&partnerID=8YFLogxK

U2 - 10.1016/j.porgcoat.2008.06.006

DO - 10.1016/j.porgcoat.2008.06.006

M3 - Article

AN - SCOPUS:55049092981

SN - 0300-9440

VL - 63

SP - 365

EP - 371

JO - Progress in Organic Coatings

JF - Progress in Organic Coatings

IS - 4

ER -

Synthesis of triglyceride-based urethane macromers and their use in copolymerization

Abstract

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Keywords

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