Synthesis of Thioethers Using Triethylamine-Activated Phosphorus Decasulfide (P410

Gulsen Turkoglu; M. Emin Cinar; Turan Ozturk

doi:10.1055/s-0035-1561673

Synthesis of Thioethers Using Triethylamine-Activated Phosphorus Decasulfide (P₄₁₀

Gulsen Turkoglu, M. Emin Cinar^*, Turan Ozturk

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The synthesis of thioethers in excellent yields was achieved under mild conditions via the displacement reaction of halogens by sulfur. The cross-reaction of 2-(α-bromoacetyl)thiophene with triethylamine-activated phosphorus decasulfide (Et₃N-P₂S₅) was elaborated by utilizing DFT calculations.

Original language	English
Pages (from-to)	3618-3624
Number of pages	7
Journal	Synthesis
Volume	48
Issue number	20
DOIs	https://doi.org/10.1055/s-0035-1561673
Publication status	Published - 17 Oct 2016

Bibliographical note

Publisher Copyright:
© Georg Thieme VerlagStuttgart · New York.

Keywords

DFT
mechanism
phosphorus decasulfide
thioethers
triethylamine activation

Access to Document

10.1055/s-0035-1561673

Cite this

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abstract = "The synthesis of thioethers in excellent yields was achieved under mild conditions via the displacement reaction of halogens by sulfur. The cross-reaction of 2-(α-bromoacetyl)thiophene with triethylamine-activated phosphorus decasulfide (Et3N-P2S5) was elaborated by utilizing DFT calculations.",

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AU - Cinar, M. Emin

AU - Ozturk, Turan

N1 - Publisher Copyright: © Georg Thieme VerlagStuttgart · New York.

PY - 2016/10/17

Y1 - 2016/10/17

N2 - The synthesis of thioethers in excellent yields was achieved under mild conditions via the displacement reaction of halogens by sulfur. The cross-reaction of 2-(α-bromoacetyl)thiophene with triethylamine-activated phosphorus decasulfide (Et3N-P2S5) was elaborated by utilizing DFT calculations.

AB - The synthesis of thioethers in excellent yields was achieved under mild conditions via the displacement reaction of halogens by sulfur. The cross-reaction of 2-(α-bromoacetyl)thiophene with triethylamine-activated phosphorus decasulfide (Et3N-P2S5) was elaborated by utilizing DFT calculations.

KW - DFT

KW - mechanism

KW - phosphorus decasulfide

KW - thioethers

KW - triethylamine activation

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DO - 10.1055/s-0035-1561673

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