Synthesis of tetrakis bromine terminated phthalocyanine and its methyl methacrylate polymers via ATRP

Tuba Çakir Çanak; Damla Yeşi̇Ldağ; Ilgın Nar; Esin Hamuryudan; İbrahim Ersin Serhatli

doi:10.3906/kim-1811-40

Synthesis of tetrakis bromine terminated phthalocyanine and its methyl methacrylate polymers via ATRP

Tuba Çakir Çanak, Damla Yeşi̇Ldağ, Ilgın Nar, Esin Hamuryudan, İbrahim Ersin Serhatli^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A phthalocyanine (Pc) initiator, tetrakis(2-bromopropyloxyester)ethylthiophthalocyaninatozinc(II) (ZnPcBr), was prepared and successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) for the first time. Bromine end groups of the synthesized Pc took part in the initiation of the MMA chain growth. Polymerization was demonstrated by monomodal molecular weight distribution of the synthesized polymers and their increasing molecular weight behavior with reaction time. UV-Vis absorption, fluorescence, and transmittance properties of the polymers were also examined. The results indicate that the ZnPc-Br-based initiator is potentially applicable in ATRP applied to MMA in order to obtain and develop functional acrylic materials.

Original language	English
Pages (from-to)	911-925
Number of pages	15
Journal	Turkish Journal of Chemistry
Volume	43
Issue number	3
DOIs	https://doi.org/10.3906/kim-1811-40
Publication status	Published - 2019

Bibliographical note

Publisher Copyright:
© TÜBİTAK

Keywords

Atom transfer radical polymerization
Phthalocyanine
Poly(methylmethacrylate)

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10.3906/kim-1811-40

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title = "Synthesis of tetrakis bromine terminated phthalocyanine and its methyl methacrylate polymers via ATRP",

abstract = "A phthalocyanine (Pc) initiator, tetrakis(2-bromopropyloxyester)ethylthiophthalocyaninatozinc(II) (ZnPcBr), was prepared and successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) for the first time. Bromine end groups of the synthesized Pc took part in the initiation of the MMA chain growth. Polymerization was demonstrated by monomodal molecular weight distribution of the synthesized polymers and their increasing molecular weight behavior with reaction time. UV-Vis absorption, fluorescence, and transmittance properties of the polymers were also examined. The results indicate that the ZnPc-Br-based initiator is potentially applicable in ATRP applied to MMA in order to obtain and develop functional acrylic materials.",

keywords = "Atom transfer radical polymerization, Phthalocyanine, Poly(methylmethacrylate)",

author = "{{\c C}akir {\c C}anak}, Tuba and Damla Ye{\c s}{\.i}Ldağ and Ilgın Nar and Esin Hamuryudan and Serhatli, {İbrahim Ersin}",

note = "Publisher Copyright: {\textcopyright} T{\"U}BİTAK",

year = "2019",

doi = "10.3906/kim-1811-40",

language = "English",

volume = "43",

pages = "911--925",

journal = "Turkish Journal of Chemistry",

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TY - JOUR

T1 - Synthesis of tetrakis bromine terminated phthalocyanine and its methyl methacrylate polymers via ATRP

AU - Çakir Çanak, Tuba

AU - Yeşi̇Ldağ, Damla

AU - Nar, Ilgın

AU - Hamuryudan, Esin

AU - Serhatli, İbrahim Ersin

N1 - Publisher Copyright: © TÜBİTAK

PY - 2019

Y1 - 2019

N2 - A phthalocyanine (Pc) initiator, tetrakis(2-bromopropyloxyester)ethylthiophthalocyaninatozinc(II) (ZnPcBr), was prepared and successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) for the first time. Bromine end groups of the synthesized Pc took part in the initiation of the MMA chain growth. Polymerization was demonstrated by monomodal molecular weight distribution of the synthesized polymers and their increasing molecular weight behavior with reaction time. UV-Vis absorption, fluorescence, and transmittance properties of the polymers were also examined. The results indicate that the ZnPc-Br-based initiator is potentially applicable in ATRP applied to MMA in order to obtain and develop functional acrylic materials.

AB - A phthalocyanine (Pc) initiator, tetrakis(2-bromopropyloxyester)ethylthiophthalocyaninatozinc(II) (ZnPcBr), was prepared and successfully applied to atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) for the first time. Bromine end groups of the synthesized Pc took part in the initiation of the MMA chain growth. Polymerization was demonstrated by monomodal molecular weight distribution of the synthesized polymers and their increasing molecular weight behavior with reaction time. UV-Vis absorption, fluorescence, and transmittance properties of the polymers were also examined. The results indicate that the ZnPc-Br-based initiator is potentially applicable in ATRP applied to MMA in order to obtain and develop functional acrylic materials.

KW - Atom transfer radical polymerization

KW - Phthalocyanine

KW - Poly(methylmethacrylate)

UR - http://www.scopus.com/inward/record.url?scp=85068853142&partnerID=8YFLogxK

U2 - 10.3906/kim-1811-40

DO - 10.3906/kim-1811-40

M3 - Article

AN - SCOPUS:85068853142

SN - 1300-0527

VL - 43

SP - 911

EP - 925

JO - Turkish Journal of Chemistry

JF - Turkish Journal of Chemistry

IS - 3

ER -

Synthesis of tetrakis bromine terminated phthalocyanine and its methyl methacrylate polymers via ATRP

Abstract

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Keywords

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