Synthesis of Poly(vitamin C) through ADMET

Serter Luleburgaz, Meir Abuaf, Umit Tunca, Gurkan Hizal, Hakan Durmaz*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

l-Ascorbic acid, commonly known as vitamin C and one of the most important biological compounds, is converted to a α,ω-diene monomer and subsequently polymerized for the first time by acyclic diene metathesis. Various experimental conditions such as polymerization medium, catalyst type, temperature, and monomer/catalyst ratio are studied. The moderate molecular weight polymers are achieved when the polymerizations are conducted under bulk conditions employing the Grubbs first generation (G1) or Hoveyda–Grubbs second generation catalyst (HG-2). In the solution case, on the other hand, low molecular weight polymers are obtained regardless of the catalyst type. Moreover, when the catalyst performances are compared, it is found that G1 produces the higher molecular weight as well as higher yield polymers with respect to the HG-2. (Figure presented.).

Original languageEnglish
Article number1600772
JournalMacromolecular Rapid Communications
Volume38
Issue number11
DOIs
Publication statusPublished - Jun 2017

Bibliographical note

Publisher Copyright:
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Funding

The authors gratefully acknowledge the Scientific and Technological Research Council of Turkey (TUBITAK) (Project No. 215Z446) for financial support. The authors also acknowledge Bogazici University Center for Life Sciences and Technologies for MALDI-ToF MS analyses.

FundersFunder number
Bogazici University Center for Life Sciences and Technologies
TUBITAK215Z446
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu

    Keywords

    • acyclic diene metathesis (ADMET)
    • bio-based polymers
    • l-ascorbic acid
    • poly(vitamin C)

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