Synthesis of poly(isobutyl vinyl ether)-graft-Poly(ethylene oxide) co-polymer with pendant methacrylate functionality and its photo-curing behavior

Elif Sezin Devrim; Muhammet U. Kahveci; M. Atilla Tasdelen; Koichi Ito; Yusuf Yagci

doi:10.1163/156855509X436085

Synthesis of poly(isobutyl vinyl ether)-graft-Poly(ethylene oxide) co-polymer with pendant methacrylate functionality and its photo-curing behavior

Elif Sezin Devrim, Muhammet U. Kahveci, M. Atilla Tasdelen, Koichi Ito, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Poly(isobutyl vinyl ether)-graft-poly(ethylene oxide) graft co-polymer with pendant methacrylate groups (PIBVE-g-PEO) was obtained by photoinitiated living cationic co-polymerization of isobutyl vinyl ether (IBVE) with α-vinyloxy-ω-methacryloyl-poly(ethylene oxide) (VE-PEO-MA) macromonomer. For this purpose, anionically prepared VE-PEO-MA hybrid macromonomer and IBVE were irradiated in the presence of diphenyl iodonium iodide and zinc iodide as photoacid generator and activator, respectively. Successful graft co-polymerization and conservation of pendant double bonds were confirmed by GPC, and ¹H-NMR and FT-IR spectral analysis. The free radical photo-cross-linking behavior of the graft co-polymer was demonstrated.

Original language	English
Pages (from-to)	265-272
Number of pages	8
Journal	Designed Monomers and Polymers
Volume	12
Issue number	3
DOIs	https://doi.org/10.1163/156855509X436085
Publication status	Published - 1 May 2009

Keywords

Graft co-polymers
Living cationic polymerization
Macromonomer
Photo-curing
Photo-polymerization

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title = "Synthesis of poly(isobutyl vinyl ether)-graft-Poly(ethylene oxide) co-polymer with pendant methacrylate functionality and its photo-curing behavior",

abstract = "Poly(isobutyl vinyl ether)-graft-poly(ethylene oxide) graft co-polymer with pendant methacrylate groups (PIBVE-g-PEO) was obtained by photoinitiated living cationic co-polymerization of isobutyl vinyl ether (IBVE) with α-vinyloxy-ω-methacryloyl-poly(ethylene oxide) (VE-PEO-MA) macromonomer. For this purpose, anionically prepared VE-PEO-MA hybrid macromonomer and IBVE were irradiated in the presence of diphenyl iodonium iodide and zinc iodide as photoacid generator and activator, respectively. Successful graft co-polymerization and conservation of pendant double bonds were confirmed by GPC, and 1H-NMR and FT-IR spectral analysis. The free radical photo-cross-linking behavior of the graft co-polymer was demonstrated.",

keywords = "Graft co-polymers, Living cationic polymerization, Macromonomer, Photo-curing, Photo-polymerization",

author = "Devrim, {Elif Sezin} and Kahveci, {Muhammet U.} and Tasdelen, {M. Atilla} and Koichi Ito and Yusuf Yagci",

year = "2009",

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doi = "10.1163/156855509X436085",

language = "English",

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T1 - Synthesis of poly(isobutyl vinyl ether)-graft-Poly(ethylene oxide) co-polymer with pendant methacrylate functionality and its photo-curing behavior

AU - Devrim, Elif Sezin

AU - Kahveci, Muhammet U.

AU - Tasdelen, M. Atilla

AU - Ito, Koichi

AU - Yagci, Yusuf

PY - 2009/5/1

Y1 - 2009/5/1

N2 - Poly(isobutyl vinyl ether)-graft-poly(ethylene oxide) graft co-polymer with pendant methacrylate groups (PIBVE-g-PEO) was obtained by photoinitiated living cationic co-polymerization of isobutyl vinyl ether (IBVE) with α-vinyloxy-ω-methacryloyl-poly(ethylene oxide) (VE-PEO-MA) macromonomer. For this purpose, anionically prepared VE-PEO-MA hybrid macromonomer and IBVE were irradiated in the presence of diphenyl iodonium iodide and zinc iodide as photoacid generator and activator, respectively. Successful graft co-polymerization and conservation of pendant double bonds were confirmed by GPC, and 1H-NMR and FT-IR spectral analysis. The free radical photo-cross-linking behavior of the graft co-polymer was demonstrated.

AB - Poly(isobutyl vinyl ether)-graft-poly(ethylene oxide) graft co-polymer with pendant methacrylate groups (PIBVE-g-PEO) was obtained by photoinitiated living cationic co-polymerization of isobutyl vinyl ether (IBVE) with α-vinyloxy-ω-methacryloyl-poly(ethylene oxide) (VE-PEO-MA) macromonomer. For this purpose, anionically prepared VE-PEO-MA hybrid macromonomer and IBVE were irradiated in the presence of diphenyl iodonium iodide and zinc iodide as photoacid generator and activator, respectively. Successful graft co-polymerization and conservation of pendant double bonds were confirmed by GPC, and 1H-NMR and FT-IR spectral analysis. The free radical photo-cross-linking behavior of the graft co-polymer was demonstrated.

KW - Graft co-polymers

KW - Living cationic polymerization

KW - Macromonomer

KW - Photo-curing

KW - Photo-polymerization

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U2 - 10.1163/156855509X436085

DO - 10.1163/156855509X436085

M3 - Article

AN - SCOPUS:69549138237

SN - 1385-772X

VL - 12

SP - 265

EP - 272

JO - Designed Monomers and Polymers

JF - Designed Monomers and Polymers

IS - 3

ER -

Synthesis of poly(isobutyl vinyl ether)-graft-Poly(ethylene oxide) co-polymer with pendant methacrylate functionality and its photo-curing behavior

Abstract

Keywords

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