TY - JOUR
T1 - Synthesis of N,N′-diallylmalonamide and its copolymer gels with acrylic acid and acrylamide
AU - Biçak, Niyazi
AU - Karaoǧlan, Sevim
AU - Senkal, Bahire Filiz
PY - 1998/3
Y1 - 1998/3
N2 - N,N′-diallylmalonamide (DAM) has been prepared via classical aminolysis of diethyl malonate with allylamine. Its structure was confirmed by elementary microanalysis as well as 1H NMR and FT-IR spectroscopy. The new diallyl monomer is water-soluble and able to copolymerize radically with water-soluble monomers, such as acrylamide and acrylic acid, to give transparent hydrogels by using K2S2O8 as initiator. Homopolymerization of DAM yields clear hydrogels with high swelling ability.
AB - N,N′-diallylmalonamide (DAM) has been prepared via classical aminolysis of diethyl malonate with allylamine. Its structure was confirmed by elementary microanalysis as well as 1H NMR and FT-IR spectroscopy. The new diallyl monomer is water-soluble and able to copolymerize radically with water-soluble monomers, such as acrylamide and acrylic acid, to give transparent hydrogels by using K2S2O8 as initiator. Homopolymerization of DAM yields clear hydrogels with high swelling ability.
UR - https://www.scopus.com/pages/publications/0006967573
U2 - 10.1002/(sici)1522-9505(19980301)255:1<13::aid-apmc13>3.3.co;2-o
DO - 10.1002/(sici)1522-9505(19980301)255:1<13::aid-apmc13>3.3.co;2-o
M3 - Article
AN - SCOPUS:0006967573
SN - 0003-3146
VL - 255
SP - 13
EP - 16
JO - Angewandte Makromolekulare Chemie
JF - Angewandte Makromolekulare Chemie
ER -