Synthesis of New 7,8-Dioxa[6]helicenes with Triazole Rings as Potential Molecular Tweezers

Nilay Kasabali; Hande Gunduz; Kerem Kaya; Volkan Kumbaraci; Naciye Talinli

doi:10.1055/s-0037-1611879

Synthesis of New 7,8-Dioxa[6]helicenes with Triazole Rings as Potential Molecular Tweezers

Nilay Kasabali, Hande Gunduz, Kerem Kaya, Volkan Kumbaraci^*, Naciye Talinli

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

This study introduces new triazole-linked host compounds, which have been synthesized from 7,8-dioxa-bisnaphthalene and 7,8-dioxa[6]helicenes. These compounds have different cavities depending on being 'v'-shaped or helicene structures. The dimeric structure of 7,8-dioxa-bisnaphthalene has also been obtained and crystal structure analysis confirmed that it contains an unusual seven-membered dihydrooxepine ring. All synthesized compounds can act as molecular tweezers for organic molecules and also metal ions.

Original language	English
Pages (from-to)	1546-1550
Number of pages	5
Journal	Synlett
Volume	30
Issue number	13
DOIs	https://doi.org/10.1055/s-0037-1611879
Publication status	Published - 2019

Bibliographical note

Publisher Copyright:
© 2019 EDP Sciences. All rights reserved.

Funding

We thank to Istanbul Technical University for financial support.IstanbulTeknikÜniversitesi (ITUBAP40621)

Funders	Funder number
Istanbul Teknik Üniversitesi	ITUBAP40621

Keywords

bisnaphthalenes
dioxahelicenes
molecular tweezers
triazoles
v-shaped molecules

Access to Document

10.1055/s-0037-1611879

Cite this

@article{5b7d128850824b97abbd42aa7850a3e4,

title = "Synthesis of New 7,8-Dioxa[6]helicenes with Triazole Rings as Potential Molecular Tweezers",

abstract = "This study introduces new triazole-linked host compounds, which have been synthesized from 7,8-dioxa-bisnaphthalene and 7,8-dioxa[6]helicenes. These compounds have different cavities depending on being 'v'-shaped or helicene structures. The dimeric structure of 7,8-dioxa-bisnaphthalene has also been obtained and crystal structure analysis confirmed that it contains an unusual seven-membered dihydrooxepine ring. All synthesized compounds can act as molecular tweezers for organic molecules and also metal ions.",

keywords = "bisnaphthalenes, dioxahelicenes, molecular tweezers, triazoles, v-shaped molecules",

author = "Nilay Kasabali and Hande Gunduz and Kerem Kaya and Volkan Kumbaraci and Naciye Talinli",

year = "2019",

doi = "10.1055/s-0037-1611879",

language = "English",

volume = "30",

pages = "1546--1550",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "13",

}

TY - JOUR

T1 - Synthesis of New 7,8-Dioxa[6]helicenes with Triazole Rings as Potential Molecular Tweezers

AU - Kasabali, Nilay

AU - Gunduz, Hande

AU - Kaya, Kerem

AU - Kumbaraci, Volkan

AU - Talinli, Naciye

PY - 2019

Y1 - 2019

N2 - This study introduces new triazole-linked host compounds, which have been synthesized from 7,8-dioxa-bisnaphthalene and 7,8-dioxa[6]helicenes. These compounds have different cavities depending on being 'v'-shaped or helicene structures. The dimeric structure of 7,8-dioxa-bisnaphthalene has also been obtained and crystal structure analysis confirmed that it contains an unusual seven-membered dihydrooxepine ring. All synthesized compounds can act as molecular tweezers for organic molecules and also metal ions.

AB - This study introduces new triazole-linked host compounds, which have been synthesized from 7,8-dioxa-bisnaphthalene and 7,8-dioxa[6]helicenes. These compounds have different cavities depending on being 'v'-shaped or helicene structures. The dimeric structure of 7,8-dioxa-bisnaphthalene has also been obtained and crystal structure analysis confirmed that it contains an unusual seven-membered dihydrooxepine ring. All synthesized compounds can act as molecular tweezers for organic molecules and also metal ions.

KW - bisnaphthalenes

KW - dioxahelicenes

KW - molecular tweezers

KW - triazoles

KW - v-shaped molecules

UR - http://www.scopus.com/inward/record.url?scp=85070107980&partnerID=8YFLogxK

U2 - 10.1055/s-0037-1611879

DO - 10.1055/s-0037-1611879

M3 - Article

AN - SCOPUS:85070107980

SN - 0936-5214

VL - 30

SP - 1546

EP - 1550

JO - Synlett

JF - Synlett

IS - 13

ER -

Synthesis of New 7,8-Dioxa[6]helicenes with Triazole Rings as Potential Molecular Tweezers

Abstract

Bibliographical note

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this