Synthesis of Mn2O3 nanopowders with urea and citric acid by solution combustion route

Esma Yilmaz; M. Seref Sonmez; Bora Derin; Filiz Cinar Sahin; Onuralp Yucel

doi:10.1007/978-3-319-51493-2_5

Synthesis of Mn₂O₃ nanopowders with urea and citric acid by solution combustion route

Esma Yilmaz^*, M. Seref Sonmez, Bora Derin, Filiz Cinar Sahin, Onuralp Yucel

^*Corresponding author for this work

Department of Metallurgical and Materials Engineering

Istanbul Technical University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

3 Citations (Scopus)

Abstract

In this study, synthesis of Mn₂O₃ powders by solution combustion route was carried out. Urea (CH₄N₂O) and citric acid (C₆H₈O₇.H₂O) was used as a fuel material in solution combustion synthesis, while manganese nitrate (Mn(NO₃)₂.4H₂O) was used as an oxidant. Surface area of Mn₂O₃ synthesised by urea was calculated as 19,37 m²/g and 25,07 m²/g after the calcination at 400 °C and 500 °C, respectively. Surface area of Mn₂O₃ synthesised by citric acid was calculated as 63,77 m²/g when fuel/oxidizer was 1/1, ignition temperature of 250 °C and calcination temperature at 500 °C. Spherical particles of Mn₂O₃ having average particle size of 50–60 nm was synthesised by using urea, while foam like porous structure of Mn₂O₃ was obtained when citric acid was used as a fuel in solution combustion synthesis. Pore diameters between 27 and 55 nm was determined for this powders.

Original language	English
Title of host publication	TMS 2017 146th Annual Meeting
Publisher	Springer International Publishing
Pages	39-46
Number of pages	8
ISBN (Print)	9783319514925
DOIs	https://doi.org/10.1007/978-3-319-51493-2_5
Publication status	Published - 2017
Event	146th Annual Meeting and Exhibition Supplemental, TMS 2017 - San Diego, United States Duration: 26 Feb 2017 → 2 Mar 2017

Publication series

Name	Minerals, Metals and Materials Series
Volume	Part F6
ISSN (Print)	2367-1181
ISSN (Electronic)	2367-1696

Conference

Conference	146th Annual Meeting and Exhibition Supplemental, TMS 2017
Country/Territory	United States
City	San Diego
Period	26/02/17 → 2/03/17

Bibliographical note

Publisher Copyright:
© The Minerals, Metals & Materials Society 2017.

Keywords

MnO
Nanopores
Nanopowders
Solution combustion synthesis

Access to Document

10.1007/978-3-319-51493-2_5

Cite this

@inproceedings{5d230194c0c442d38327a803f0c787e0,

title = "Synthesis of Mn2O3 nanopowders with urea and citric acid by solution combustion route",

abstract = "In this study, synthesis of Mn2O3 powders by solution combustion route was carried out. Urea (CH4N2O) and citric acid (C6H8O7.H2O) was used as a fuel material in solution combustion synthesis, while manganese nitrate (Mn(NO3)2.4H2O) was used as an oxidant. Surface area of Mn2O3 synthesised by urea was calculated as 19,37 m2/g and 25,07 m2/g after the calcination at 400 °C and 500 °C, respectively. Surface area of Mn2O3 synthesised by citric acid was calculated as 63,77 m2/g when fuel/oxidizer was 1/1, ignition temperature of 250 °C and calcination temperature at 500 °C. Spherical particles of Mn2O3 having average particle size of 50–60 nm was synthesised by using urea, while foam like porous structure of Mn2O3 was obtained when citric acid was used as a fuel in solution combustion synthesis. Pore diameters between 27 and 55 nm was determined for this powders.",

keywords = "MnO, Nanopores, Nanopowders, Solution combustion synthesis",

author = "Esma Yilmaz and Sonmez, {M. Seref} and Bora Derin and Sahin, {Filiz Cinar} and Onuralp Yucel",

note = "Publisher Copyright: {\textcopyright} The Minerals, Metals & Materials Society 2017.; 146th Annual Meeting and Exhibition Supplemental, TMS 2017 ; Conference date: 26-02-2017 Through 02-03-2017",

year = "2017",

doi = "10.1007/978-3-319-51493-2_5",

language = "English",

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address = "Switzerland",

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Yilmaz, E, Sonmez, MS , Derin, B , Sahin, FC & Yucel, O 2017, Synthesis of Mn₂O₃ nanopowders with urea and citric acid by solution combustion route. in TMS 2017 146th Annual Meeting. Minerals, Metals and Materials Series, vol. Part F6, Springer International Publishing, pp. 39-46, 146th Annual Meeting and Exhibition Supplemental, TMS 2017, San Diego, United States, 26/02/17. https://doi.org/10.1007/978-3-319-51493-2_5

Synthesis of Mn₂O₃ nanopowders with urea and citric acid by solution combustion route. / Yilmaz, Esma; Sonmez, M. Seref ; Derin, Bora et al.
TMS 2017 146th Annual Meeting. Springer International Publishing, 2017. p. 39-46 (Minerals, Metals and Materials Series; Vol. Part F6).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Synthesis of Mn2O3 nanopowders with urea and citric acid by solution combustion route

AU - Yilmaz, Esma

AU - Sonmez, M. Seref

AU - Derin, Bora

AU - Sahin, Filiz Cinar

AU - Yucel, Onuralp

PY - 2017

Y1 - 2017

N2 - In this study, synthesis of Mn2O3 powders by solution combustion route was carried out. Urea (CH4N2O) and citric acid (C6H8O7.H2O) was used as a fuel material in solution combustion synthesis, while manganese nitrate (Mn(NO3)2.4H2O) was used as an oxidant. Surface area of Mn2O3 synthesised by urea was calculated as 19,37 m2/g and 25,07 m2/g after the calcination at 400 °C and 500 °C, respectively. Surface area of Mn2O3 synthesised by citric acid was calculated as 63,77 m2/g when fuel/oxidizer was 1/1, ignition temperature of 250 °C and calcination temperature at 500 °C. Spherical particles of Mn2O3 having average particle size of 50–60 nm was synthesised by using urea, while foam like porous structure of Mn2O3 was obtained when citric acid was used as a fuel in solution combustion synthesis. Pore diameters between 27 and 55 nm was determined for this powders.

AB - In this study, synthesis of Mn2O3 powders by solution combustion route was carried out. Urea (CH4N2O) and citric acid (C6H8O7.H2O) was used as a fuel material in solution combustion synthesis, while manganese nitrate (Mn(NO3)2.4H2O) was used as an oxidant. Surface area of Mn2O3 synthesised by urea was calculated as 19,37 m2/g and 25,07 m2/g after the calcination at 400 °C and 500 °C, respectively. Surface area of Mn2O3 synthesised by citric acid was calculated as 63,77 m2/g when fuel/oxidizer was 1/1, ignition temperature of 250 °C and calcination temperature at 500 °C. Spherical particles of Mn2O3 having average particle size of 50–60 nm was synthesised by using urea, while foam like porous structure of Mn2O3 was obtained when citric acid was used as a fuel in solution combustion synthesis. Pore diameters between 27 and 55 nm was determined for this powders.

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T2 - 146th Annual Meeting and Exhibition Supplemental, TMS 2017

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