Synthesis of liquid crystalline graft and block copolymers by sequential cationic and free-radical polymerizations

Ersin I. Serhatli; Giancarlo Galli; Yusuf Yagci; Michele Laus; Sante A. Angeloni; Emo Chiellini

doi:10.1163/156855599X00089

Synthesis of liquid crystalline graft and block copolymers by sequential cationic and free-radical polymerizations

Ersin I. Serhatli, Giancarlo Galli^*, Yusuf Yagci, Michele Laus, Sante A. Angeloni, Emo Chiellini

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

New graft and block copolymers were synthesized by two procedures, each consisting of a sequence of cationic and free-radical polymerization reactions. One polymer component was a liquid crystalline side-group polymer, with the other polymer component being incorporated in crystalline grafts or in amorphous blocks. The copolymers were microphase-separated and underwent thermal transitions (glass, melting, isotropization) of each individual component.

Original language	English
Pages (from-to)	259-265
Number of pages	7
Journal	Designed Monomers and Polymers
Volume	2
Issue number	3
DOIs	https://doi.org/10.1163/156855599X00089
Publication status	Published - 1999

Keywords

Block copolymers
Graft copolymers
Liquid crystals

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10.1163/156855599X00089

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abstract = "New graft and block copolymers were synthesized by two procedures, each consisting of a sequence of cationic and free-radical polymerization reactions. One polymer component was a liquid crystalline side-group polymer, with the other polymer component being incorporated in crystalline grafts or in amorphous blocks. The copolymers were microphase-separated and underwent thermal transitions (glass, melting, isotropization) of each individual component.",

keywords = "Block copolymers, Graft copolymers, Liquid crystals",

author = "Serhatli, {Ersin I.} and Giancarlo Galli and Yusuf Yagci and Michele Laus and Angeloni, {Sante A.} and Emo Chiellini",

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AU - Serhatli, Ersin I.

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AU - Yagci, Yusuf

AU - Laus, Michele

AU - Angeloni, Sante A.

AU - Chiellini, Emo

PY - 1999

Y1 - 1999

N2 - New graft and block copolymers were synthesized by two procedures, each consisting of a sequence of cationic and free-radical polymerization reactions. One polymer component was a liquid crystalline side-group polymer, with the other polymer component being incorporated in crystalline grafts or in amorphous blocks. The copolymers were microphase-separated and underwent thermal transitions (glass, melting, isotropization) of each individual component.

AB - New graft and block copolymers were synthesized by two procedures, each consisting of a sequence of cationic and free-radical polymerization reactions. One polymer component was a liquid crystalline side-group polymer, with the other polymer component being incorporated in crystalline grafts or in amorphous blocks. The copolymers were microphase-separated and underwent thermal transitions (glass, melting, isotropization) of each individual component.

KW - Block copolymers

KW - Graft copolymers

KW - Liquid crystals

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DO - 10.1163/156855599X00089

M3 - Article

AN - SCOPUS:0009741390

SN - 1385-772X

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JO - Designed Monomers and Polymers

JF - Designed Monomers and Polymers

IS - 3

ER -

Synthesis of liquid crystalline graft and block copolymers by sequential cationic and free-radical polymerizations

Abstract

Keywords

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