Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization

Metin H. Acar; Niyazi Bicak

doi:10.1002/pola.10716

Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization

Metin H. Acar^*, Niyazi Bicak

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr₂ was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.

Original language	English
Pages (from-to)	1677-1680
Number of pages	4
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	41
Issue number	11
DOIs	https://doi.org/10.1002/pola.10716
Publication status	Published - 1 Jun 2003

Keywords

Atom transfer radical polymerization (ATRP)
Homogeneous polymerization
Ligand
Living radical polymerization
Metal-organic catalysts / organometallic catalysts

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10.1002/pola.10716

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title = "Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization",

abstract = "The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr2 was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.",

keywords = "Atom transfer radical polymerization (ATRP), Homogeneous polymerization, Ligand, Living radical polymerization, Metal-organic catalysts / organometallic catalysts",

author = "Acar, {Metin H.} and Niyazi Bicak",

year = "2003",

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T1 - Synthesis of hexylated triethylenetetramine

T2 - New ligand for homogeneous atom transfer radical polymerization

AU - Acar, Metin H.

AU - Bicak, Niyazi

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Y1 - 2003/6/1

N2 - The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr2 was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.

AB - The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr2 was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.

KW - Atom transfer radical polymerization (ATRP)

KW - Homogeneous polymerization

KW - Ligand

KW - Living radical polymerization

KW - Metal-organic catalysts / organometallic catalysts

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U2 - 10.1002/pola.10716

DO - 10.1002/pola.10716

M3 - Article

AN - SCOPUS:0037809270

SN - 0887-624X

VL - 41

SP - 1677

EP - 1680

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 11

ER -

Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization

Abstract

Keywords

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