TY - JOUR
T1 - Synthesis of block copolymers by the combination of chain transfer polymerization and initer process
AU - Demircioglu, Perihan
AU - Acar, Metin H.
AU - Yagci, Yusuf
PY - 1992/11/25
Y1 - 1992/11/25
N2 - Radical polymerizations of styrene (St) and methyl methacrylate (MMA) were carried out in the presence of tri phenylmethyl mercaptan (TPMM) as a chain transfer agent to give trityl (triphenylmethyl) terminated polymers. Transfer constants were found to be 17.8 and 0.71 for St and MMA, respectively. Trityl terminated polymers served as thermal “INITERS” for polymerization of vinyl monomers which proceeded via a quasi‐living radical mechanism. This procedure makes it possible to prepare block copolymers. © John Wiley & Sons, Inc.
AB - Radical polymerizations of styrene (St) and methyl methacrylate (MMA) were carried out in the presence of tri phenylmethyl mercaptan (TPMM) as a chain transfer agent to give trityl (triphenylmethyl) terminated polymers. Transfer constants were found to be 17.8 and 0.71 for St and MMA, respectively. Trityl terminated polymers served as thermal “INITERS” for polymerization of vinyl monomers which proceeded via a quasi‐living radical mechanism. This procedure makes it possible to prepare block copolymers. © John Wiley & Sons, Inc.
UR - http://www.scopus.com/inward/record.url?scp=0026945118&partnerID=8YFLogxK
U2 - 10.1002/app.1992.070460912
DO - 10.1002/app.1992.070460912
M3 - Article
AN - SCOPUS:0026945118
SN - 0021-8995
VL - 46
SP - 1639
EP - 1643
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
IS - 9
ER -