Synthesis of Block Copolymers by Combination of an Activated Monomer and Free Radical Polymerization Mechanism

Yusuf Yagci; I. Ersin Serhatli; Przemyslaw Kubisa; Tadeusz Biedron

doi:10.1021/ma00062a001

Synthesis of Block Copolymers by Combination of an Activated Monomer and Free Radical Polymerization Mechanism

Yusuf Yagci^*, I. Ersin Serhatli, Przemyslaw Kubisa, Tadeusz Biedron

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

Epichlorohydrin (ECH) was polymerized by an activated monomer mechanism (AM) in the presence of 4,4′-azobis(4-cyanopentanol). Spectroscopic and degradation studies showed that polymers obtained via this initiation method contained an azo linkage in the main chain. These prepolymers were employed in the polymerization of styrene (St) to yield block copolymers.

Original language	English
Pages (from-to)	2397-2399
Number of pages	3
Journal	Macromolecules
Volume	26
Issue number	10
DOIs	https://doi.org/10.1021/ma00062a001
Publication status	Published - 10 May 1993

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title = "Synthesis of Block Copolymers by Combination of an Activated Monomer and Free Radical Polymerization Mechanism",

abstract = "Epichlorohydrin (ECH) was polymerized by an activated monomer mechanism (AM) in the presence of 4,4′-azobis(4-cyanopentanol). Spectroscopic and degradation studies showed that polymers obtained via this initiation method contained an azo linkage in the main chain. These prepolymers were employed in the polymerization of styrene (St) to yield block copolymers.",

author = "Yusuf Yagci and Serhatli, {I. Ersin} and Przemyslaw Kubisa and Tadeusz Biedron",

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T1 - Synthesis of Block Copolymers by Combination of an Activated Monomer and Free Radical Polymerization Mechanism

AU - Yagci, Yusuf

AU - Serhatli, I. Ersin

AU - Kubisa, Przemyslaw

AU - Biedron, Tadeusz

PY - 1993/5/10

Y1 - 1993/5/10

N2 - Epichlorohydrin (ECH) was polymerized by an activated monomer mechanism (AM) in the presence of 4,4′-azobis(4-cyanopentanol). Spectroscopic and degradation studies showed that polymers obtained via this initiation method contained an azo linkage in the main chain. These prepolymers were employed in the polymerization of styrene (St) to yield block copolymers.

AB - Epichlorohydrin (ECH) was polymerized by an activated monomer mechanism (AM) in the presence of 4,4′-azobis(4-cyanopentanol). Spectroscopic and degradation studies showed that polymers obtained via this initiation method contained an azo linkage in the main chain. These prepolymers were employed in the polymerization of styrene (St) to yield block copolymers.

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U2 - 10.1021/ma00062a001

DO - 10.1021/ma00062a001

M3 - Article

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JO - Macromolecules

JF - Macromolecules

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ER -

Synthesis of Block Copolymers by Combination of an Activated Monomer and Free Radical Polymerization Mechanism

Abstract

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