Synthesis of aromatic poly(ether ketone)s with ferrocene units in the main chain

Ümit Tunca

doi:10.1002/apmc.1997.052530107

Synthesis of aromatic poly(ether ketone)s with ferrocene units in the main chain

Ümit Tunca^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Aromatic poly(ether ketone)s with ferrocene units in the main chain were prepared by direct polycondensation of 1,1′-ferrocenedicarboxylic acid with diphenyl ether or 1,4-diphenoxybenzene using various catalysts such as trifluoromethanesulfonic acid (triflic acid), a combination of methanesulfonic acid/P₂O₅ (Eaton's reagent) or a combination of triflic acid/P₂O₅. Polycondensations at room temperature for 24 h gave poly(arylene ether ketone)s with inherent viscosities up to 40 mL g^-1. Monoacylation of diphenyl ether with ferrocenecarboxylic acid was studied in detail in order to show the efficiency of polymer formation employing Eaton's reagent as catalyst and solvent.

Original language	English
Pages (from-to)	89-97
Number of pages	9
Journal	Angewandte Makromolekulare Chemie
Volume	253
DOIs	https://doi.org/10.1002/apmc.1997.052530107
Publication status	Published - Dec 1997

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10.1002/apmc.1997.052530107

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title = "Synthesis of aromatic poly(ether ketone)s with ferrocene units in the main chain",

abstract = "Aromatic poly(ether ketone)s with ferrocene units in the main chain were prepared by direct polycondensation of 1,1′-ferrocenedicarboxylic acid with diphenyl ether or 1,4-diphenoxybenzene using various catalysts such as trifluoromethanesulfonic acid (triflic acid), a combination of methanesulfonic acid/P2O5 (Eaton's reagent) or a combination of triflic acid/P2O5. Polycondensations at room temperature for 24 h gave poly(arylene ether ketone)s with inherent viscosities up to 40 mL g-1. Monoacylation of diphenyl ether with ferrocenecarboxylic acid was studied in detail in order to show the efficiency of polymer formation employing Eaton's reagent as catalyst and solvent.",

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AU - Tunca, Ümit

PY - 1997/12

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N2 - Aromatic poly(ether ketone)s with ferrocene units in the main chain were prepared by direct polycondensation of 1,1′-ferrocenedicarboxylic acid with diphenyl ether or 1,4-diphenoxybenzene using various catalysts such as trifluoromethanesulfonic acid (triflic acid), a combination of methanesulfonic acid/P2O5 (Eaton's reagent) or a combination of triflic acid/P2O5. Polycondensations at room temperature for 24 h gave poly(arylene ether ketone)s with inherent viscosities up to 40 mL g-1. Monoacylation of diphenyl ether with ferrocenecarboxylic acid was studied in detail in order to show the efficiency of polymer formation employing Eaton's reagent as catalyst and solvent.

AB - Aromatic poly(ether ketone)s with ferrocene units in the main chain were prepared by direct polycondensation of 1,1′-ferrocenedicarboxylic acid with diphenyl ether or 1,4-diphenoxybenzene using various catalysts such as trifluoromethanesulfonic acid (triflic acid), a combination of methanesulfonic acid/P2O5 (Eaton's reagent) or a combination of triflic acid/P2O5. Polycondensations at room temperature for 24 h gave poly(arylene ether ketone)s with inherent viscosities up to 40 mL g-1. Monoacylation of diphenyl ether with ferrocenecarboxylic acid was studied in detail in order to show the efficiency of polymer formation employing Eaton's reagent as catalyst and solvent.

UR - https://www.scopus.com/pages/publications/22944435621

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DO - 10.1002/apmc.1997.052530107

M3 - Article

AN - SCOPUS:22944435621

SN - 0003-3146

VL - 253

SP - 89

EP - 97

JO - Angewandte Makromolekulare Chemie

JF - Angewandte Makromolekulare Chemie

ER -

Synthesis of aromatic poly(ether ketone)s with ferrocene units in the main chain

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