Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst

Ahmet Kilic; Ahmet Arif Palali; Mustafa Durgun; Zeynep Tasci; Mahmut Ulusoy; Metin Dagdevren; Ismail Yilmaz

doi:10.1016/j.ica.2012.09.020

Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst

Ahmet Kilic^*
, Ahmet Arif Palali
, Mustafa Durgun
, Zeynep Tasci
, Mahmut Ulusoy
, Metin Dagdevren
, Ismail Yilmaz

^*Corresponding author for this work

Department of Chemistry

Harran University
Mugla Sıtkı Kocman University
Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by ¹H and ¹³C NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)₂] complex (2). Then, the intramolecular O-H⋯O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)₂Cu₂(N-N) ₂](ClO₄)₂ oxime complexes (3-7) where N-N = 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3′-dicarboxy-2, 2′-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime) ₂] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes.

Original language	English
Pages (from-to)	635-644
Number of pages	10
Journal	Inorganica Chimica Acta
Volume	394
DOIs	https://doi.org/10.1016/j.ica.2012.09.020
Publication status	Published - 1 Jan 2013

Funding

This work was supported by the Technological and Scientific Research Council of Turkey TUBITAK (TBAG Project No. 111T944) and the Research Fund of Harran University (HUBAK Projects Nos. 1055 and 1042, Sanliurfa, Turkey).

Funders	Funder number
Technological and Scientific Research Council of Turkey TUBITAK	111T944
Harran Üniversitesi	1055, 1042

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 13 Climate Action

Keywords

Carbon dioxide
Cyclic carbonate
Electrochemistry
Mass spectra
Oxime complexes

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10.1016/j.ica.2012.09.020

Cite this

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title = "Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst",

abstract = "Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by 1H and 13C NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)2] complex (2). Then, the intramolecular O-H⋯O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)2Cu2(N-N) 2](ClO4)2 oxime complexes (3-7) where N-N = 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3′-dicarboxy-2, 2′-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime) 2] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes.",

keywords = "Carbon dioxide, Cyclic carbonate, Electrochemistry, Mass spectra, Oxime complexes",

author = "Ahmet Kilic and Palali, \{Ahmet Arif\} and Mustafa Durgun and Zeynep Tasci and Mahmut Ulusoy and Metin Dagdevren and Ismail Yilmaz",

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doi = "10.1016/j.ica.2012.09.020",

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T1 - Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst

AU - Kilic, Ahmet

AU - Palali, Ahmet Arif

AU - Durgun, Mustafa

AU - Tasci, Zeynep

AU - Ulusoy, Mahmut

AU - Dagdevren, Metin

AU - Yilmaz, Ismail

PY - 2013/1/1

Y1 - 2013/1/1

N2 - Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by 1H and 13C NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)2] complex (2). Then, the intramolecular O-H⋯O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)2Cu2(N-N) 2](ClO4)2 oxime complexes (3-7) where N-N = 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3′-dicarboxy-2, 2′-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime) 2] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes.

AB - Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by 1H and 13C NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)2] complex (2). Then, the intramolecular O-H⋯O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)2Cu2(N-N) 2](ClO4)2 oxime complexes (3-7) where N-N = 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3′-dicarboxy-2, 2′-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime) 2] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes.

KW - Carbon dioxide

KW - Cyclic carbonate

KW - Electrochemistry

KW - Mass spectra

KW - Oxime complexes

UR - https://www.scopus.com/pages/publications/84868257258

U2 - 10.1016/j.ica.2012.09.020

DO - 10.1016/j.ica.2012.09.020

M3 - Article

AN - SCOPUS:84868257258

SN - 0020-1693

VL - 394

SP - 635

EP - 644

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst

Abstract

Funding

UN SDGs

Keywords

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