TY - JOUR
T1 - Synthesis, characterization and redox properties of a new vic-dioxime and its transition metal complexes
AU - Tas, Esref
AU - Ulusoy, Mahmut
AU - Guler, Mehmet
AU - Yilmaz, Ismail
PY - 2004/3
Y1 - 2004/3
N2 - A novel vic-dioxime, 1,2 dihydroxyimino-1-p-tolyl-3-aza-6-morpholine heptane (LH2) was prepared by reacting anti-p-tolylchloroglyoxime with 4-(3-aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal-ligand ratio of 1:2 were prepared using CoII, CuII and NiII salts. The ligand and its complexes were characterized by elemental analyses, FT-IR, u.v.-vis., 1H- and 13C-n.m.r. spectra, magnetic susceptibility measurements, thermogravimetric analyses (t.g.a.), and by cyclic voltammetry.
AB - A novel vic-dioxime, 1,2 dihydroxyimino-1-p-tolyl-3-aza-6-morpholine heptane (LH2) was prepared by reacting anti-p-tolylchloroglyoxime with 4-(3-aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal-ligand ratio of 1:2 were prepared using CoII, CuII and NiII salts. The ligand and its complexes were characterized by elemental analyses, FT-IR, u.v.-vis., 1H- and 13C-n.m.r. spectra, magnetic susceptibility measurements, thermogravimetric analyses (t.g.a.), and by cyclic voltammetry.
UR - http://www.scopus.com/inward/record.url?scp=1842451769&partnerID=8YFLogxK
U2 - 10.1023/B:TMCH.0000019417.35877.b9
DO - 10.1023/B:TMCH.0000019417.35877.b9
M3 - Article
AN - SCOPUS:1842451769
SN - 0340-4285
VL - 29
SP - 180
EP - 184
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 2
ER -