Synthesis, characterization and redox properties of a new vic-dioxime and its transition metal complexes

Esref Tas; Mahmut Ulusoy; Mehmet Guler; Ismail Yilmaz

doi:10.1023/B:TMCH.0000019417.35877.b9

Synthesis, characterization and redox properties of a new vic-dioxime and its transition metal complexes

Esref Tas^*, Mahmut Ulusoy, Mehmet Guler, Ismail Yilmaz

^*Corresponding author for this work

Department of Chemistry

Harran University

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

A novel vic-dioxime, 1,2 dihydroxyimino-1-p-tolyl-3-aza-6-morpholine heptane (LH₂) was prepared by reacting anti-p-tolylchloroglyoxime with 4-(3-aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal-ligand ratio of 1:2 were prepared using Co^II, Cu^II and Ni^II salts. The ligand and its complexes were characterized by elemental analyses, FT-IR, u.v.-vis., ¹H- and ¹³C-n.m.r. spectra, magnetic susceptibility measurements, thermogravimetric analyses (t.g.a.), and by cyclic voltammetry.

Original language	English
Pages (from-to)	180-184
Number of pages	5
Journal	Transition Metal Chemistry
Volume	29
Issue number	2
DOIs	https://doi.org/10.1023/B:TMCH.0000019417.35877.b9
Publication status	Published - Mar 2004

Funding

This work was supported by the Research Fund of Harran University (Brant-HUBAK-343). We thank the V.T. Kasumov for helpful discussions and for the use of e.s.r. equipment.

Funders	Funder number
Harran Üniversitesi	Brant-HUBAK-343

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abstract = "A novel vic-dioxime, 1,2 dihydroxyimino-1-p-tolyl-3-aza-6-morpholine heptane (LH2) was prepared by reacting anti-p-tolylchloroglyoxime with 4-(3-aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal-ligand ratio of 1:2 were prepared using CoII, CuII and NiII salts. The ligand and its complexes were characterized by elemental analyses, FT-IR, u.v.-vis., 1H- and 13C-n.m.r. spectra, magnetic susceptibility measurements, thermogravimetric analyses (t.g.a.), and by cyclic voltammetry.",

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AU - Yilmaz, Ismail

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AB - A novel vic-dioxime, 1,2 dihydroxyimino-1-p-tolyl-3-aza-6-morpholine heptane (LH2) was prepared by reacting anti-p-tolylchloroglyoxime with 4-(3-aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal-ligand ratio of 1:2 were prepared using CoII, CuII and NiII salts. The ligand and its complexes were characterized by elemental analyses, FT-IR, u.v.-vis., 1H- and 13C-n.m.r. spectra, magnetic susceptibility measurements, thermogravimetric analyses (t.g.a.), and by cyclic voltammetry.

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JO - Transition Metal Chemistry

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ER -

Synthesis, characterization and redox properties of a new vic-dioxime and its transition metal complexes

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