Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s

Ayfer Yildirim; Baris Kiskan; A. Levent Demirel; Yusuf Yagci

doi:10.1016/j.eurpolymj.2006.07.019

Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s

Ayfer Yildirim, Baris Kiskan, A. Levent Demirel, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and ¹H-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM).

Original language	English
Pages (from-to)	3006-3014
Number of pages	9
Journal	European Polymer Journal
Volume	42
Issue number	11
DOIs	https://doi.org/10.1016/j.eurpolymj.2006.07.019
Publication status	Published - Nov 2006

Funding

The authors would like to thank DPT (Turkish State Planning Association), Project no: 90192, for the financial support.

Funders	Funder number
Turkish State Planning Association	90192

Keywords

Naphthoxazine
Poly(propyleneoxide) amine
Polybenzoxazine
Thermoset

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10.1016/j.eurpolymj.2006.07.019

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title = "Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s",

abstract = "Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and 1H-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM).",

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author = "Ayfer Yildirim and Baris Kiskan and Demirel, \{A. Levent\} and Yusuf Yagci",

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AU - Yildirim, Ayfer

AU - Kiskan, Baris

AU - Demirel, A. Levent

AU - Yagci, Yusuf

PY - 2006/11

Y1 - 2006/11

N2 - Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and 1H-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM).

AB - Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and 1H-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM).

KW - Naphthoxazine

KW - Poly(propyleneoxide) amine

KW - Polybenzoxazine

KW - Thermoset

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M3 - Article

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VL - 42

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EP - 3014

JO - European Polymer Journal

JF - European Polymer Journal

IS - 11

ER -

Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s

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