Synthesis, characterization and photovoltaic behaviours of peripheral and non-peripheral tetra-[4-(4-octylpiperazin-1-yl)phenoxy] substituted zinc(II), cobalt(II), copper(II) and indium(III) phthalocyanines

Gamze Özgül Artuç; Ahmet Altındal; Belkız Bilgin Eran; Mustafa Bulut

doi:10.1016/j.ica.2019.02.042

Synthesis, characterization and photovoltaic behaviours of peripheral and non-peripheral tetra-[4-(4-octylpiperazin-1-yl)phenoxy] substituted zinc(II), cobalt(II), copper(II) and indium(III) phthalocyanines

Gamze Özgül Artuç^*
, Ahmet Altındal
, Belkız Bilgin Eran
, Mustafa Bulut

^*Corresponding author for this work

Yildiz Technical University
Yeni Yuzyil University
Marmara University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The synthesis of zinc(II), cobalt(II), copper(II) and indium(III)(OAc) phthalocyanines carrying four 4-(4-octylpiperazin-1-yl)phenoxy moieties in peripheral/non-peripheral positions were performed by the cyclotetramerization of compounds 4-[4-(4-octylpiperazin-1-yl)phenoxy]phthalonitrile or 3-[4-(4-octylpiperazin-1-yl)phenoxy]phthalonitrile with respective metal salts. The novel phthalonitriles and phthalocyanines were characterized by elemental and spectroscopic analysis, including ¹H NMR, ¹³C NMR, FT-IR, UV–Vis spectral and MALDI-TOF mass data. To clarify the influence of the position of substituent group and the variety of the central metal atom on the photovoltaic performance, bulk heterojunction devices by using phthalocyanines with different blend ratio, as donor was fabricated and characterized.

Original language	English
Pages (from-to)	35-44
Number of pages	10
Journal	Inorganica Chimica Acta
Volume	490
DOIs	https://doi.org/10.1016/j.ica.2019.02.042
Publication status	Published - 1 May 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 Elsevier B.V.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

BHJ
Conversion efficiency
PCBM
Phthalocyanine

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title = "Synthesis, characterization and photovoltaic behaviours of peripheral and non-peripheral tetra-[4-(4-octylpiperazin-1-yl)phenoxy] substituted zinc(II), cobalt(II), copper(II) and indium(III) phthalocyanines",

abstract = "The synthesis of zinc(II), cobalt(II), copper(II) and indium(III)(OAc) phthalocyanines carrying four 4-(4-octylpiperazin-1-yl)phenoxy moieties in peripheral/non-peripheral positions were performed by the cyclotetramerization of compounds 4-[4-(4-octylpiperazin-1-yl)phenoxy]phthalonitrile or 3-[4-(4-octylpiperazin-1-yl)phenoxy]phthalonitrile with respective metal salts. The novel phthalonitriles and phthalocyanines were characterized by elemental and spectroscopic analysis, including 1H NMR, 13C NMR, FT-IR, UV–Vis spectral and MALDI-TOF mass data. To clarify the influence of the position of substituent group and the variety of the central metal atom on the photovoltaic performance, bulk heterojunction devices by using phthalocyanines with different blend ratio, as donor was fabricated and characterized.",

keywords = "BHJ, Conversion efficiency, PCBM, Phthalocyanine",

author = "Artu{\c c}, \{Gamze {\"O}zg{\"u}l\} and Ahmet Altındal and Eran, \{Belkız Bilgin\} and Mustafa Bulut",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = may,

day = "1",

doi = "10.1016/j.ica.2019.02.042",

language = "English",

volume = "490",

pages = "35--44",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

}

Synthesis, characterization and photovoltaic behaviours of peripheral and non-peripheral tetra-[4-(4-octylpiperazin-1-yl)phenoxy] substituted zinc(II), cobalt(II), copper(II) and indium(III) phthalocyanines. / Artuç, Gamze Özgül; Altındal, Ahmet; Eran, Belkız Bilgin et al.
In: Inorganica Chimica Acta, Vol. 490, 01.05.2019, p. 35-44.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, characterization and photovoltaic behaviours of peripheral and non-peripheral tetra-[4-(4-octylpiperazin-1-yl)phenoxy] substituted zinc(II), cobalt(II), copper(II) and indium(III) phthalocyanines

AU - Artuç, Gamze Özgül

AU - Altındal, Ahmet

AU - Eran, Belkız Bilgin

AU - Bulut, Mustafa

PY - 2019/5/1

Y1 - 2019/5/1

N2 - The synthesis of zinc(II), cobalt(II), copper(II) and indium(III)(OAc) phthalocyanines carrying four 4-(4-octylpiperazin-1-yl)phenoxy moieties in peripheral/non-peripheral positions were performed by the cyclotetramerization of compounds 4-[4-(4-octylpiperazin-1-yl)phenoxy]phthalonitrile or 3-[4-(4-octylpiperazin-1-yl)phenoxy]phthalonitrile with respective metal salts. The novel phthalonitriles and phthalocyanines were characterized by elemental and spectroscopic analysis, including 1H NMR, 13C NMR, FT-IR, UV–Vis spectral and MALDI-TOF mass data. To clarify the influence of the position of substituent group and the variety of the central metal atom on the photovoltaic performance, bulk heterojunction devices by using phthalocyanines with different blend ratio, as donor was fabricated and characterized.

AB - The synthesis of zinc(II), cobalt(II), copper(II) and indium(III)(OAc) phthalocyanines carrying four 4-(4-octylpiperazin-1-yl)phenoxy moieties in peripheral/non-peripheral positions were performed by the cyclotetramerization of compounds 4-[4-(4-octylpiperazin-1-yl)phenoxy]phthalonitrile or 3-[4-(4-octylpiperazin-1-yl)phenoxy]phthalonitrile with respective metal salts. The novel phthalonitriles and phthalocyanines were characterized by elemental and spectroscopic analysis, including 1H NMR, 13C NMR, FT-IR, UV–Vis spectral and MALDI-TOF mass data. To clarify the influence of the position of substituent group and the variety of the central metal atom on the photovoltaic performance, bulk heterojunction devices by using phthalocyanines with different blend ratio, as donor was fabricated and characterized.

KW - BHJ

KW - Conversion efficiency

KW - PCBM

KW - Phthalocyanine

UR - https://www.scopus.com/pages/publications/85062428198

U2 - 10.1016/j.ica.2019.02.042

DO - 10.1016/j.ica.2019.02.042

M3 - Article

AN - SCOPUS:85062428198

SN - 0020-1693

VL - 490

SP - 35

EP - 44

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Synthesis, characterization and photovoltaic behaviours of peripheral and non-peripheral tetra-[4-(4-octylpiperazin-1-yl)phenoxy] substituted zinc(II), cobalt(II), copper(II) and indium(III) phthalocyanines

Abstract

Bibliographical note

UN SDGs

Keywords

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