Abstract
The design of novel substituted phthalocyanines closely follows the requirement of their planned applications. In this study, synthesize of novel pyridone derivatives metal-free and symmetrical cobalt(II) phthalocyanines was carried out to improve brightness. For this purpose; starting with 4-nitrophthalonitrile and 4-hydroxy-6-methyl-3-nitro-2-pyridone, 4-(6-methyl-3-nitro-2-oxo-1,2-dihydropyridin-4-yloxy)phthalonitrile was prepared. Then 2(3),9(10),16(17),23(24)-tetrakis[6-methyl-3-nitro-2-oxo-1,2-dihydropyridin-4-yloxy] metal-free phthalocyaninato and 2(3),9(10), 16(17),23(24)-tetrakis[6-methyl-3-nitro-2-oxo-1,2-dihydropyridin-4-yloxy] phthalocyaninato Co(II) were synthesized by using 4-(6-methyl-3-nitro-2-oxo-1,2-dihydropyridin-4-yloxy)phthalonitrile, lithium metal and cobalt(II) acetate tetrahydrate in amyl alcohol, respectively. The sensing behavior of the film of derivatives metal-free and symmetrical cobalt(II) phthalocyanines for the online detection of heavy metal ions in water samples was investigated by utilizing an AT-cut quartz crystal resonator. It was observed that the adsorption of the analytes on the coating surface cause a reversible negative frequency shift of the resonator. Quartz crystal microbalance (QCM) functionalized with phthalocyanine, derivatives metal-free and symmetrical cobalt(II) phthalocyanines, are demonstrated to be sensors for the detection of heavy metal ions like Cd2+, Zn2+, Cu2+, Cr2+ and Co2+. Thus, QCM based sensor arrays are considered a promising platform for the direct analysis of aqueous samples.
Original language | English |
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Pages (from-to) | 1457-1462 |
Number of pages | 6 |
Journal | Journal of Porphyrins and Phthalocyanines |
Volume | 20 |
Issue number | 12 |
DOIs | |
Publication status | Published - 1 Dec 2016 |
Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2016 World Scientific Publishing Company.
Keywords
- cobalt
- detection
- heavy metal
- metal-free
- phthalocyanine
- pyridone
- sensitivity