Synthesis and solution properties of phthalocyanines substituted with four crown ethers

Esin Hamuryudan

doi:10.1016/j.dyepig.2005.01.018

Synthesis and solution properties of phthalocyanines substituted with four crown ethers

Esin Hamuryudan^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Metal-free and metal phthalocyanines (M = Ni, Zn, Co) substituted with four benzo-15-crown-5 units through oxy-bridges have been synthesized from a new phthalonitrile derivative, 1-{[(benzo-15-crown-5)-4′-yl]oxy}phthalonitrile (3). The newly prepared compounds have been characterized by elemental analyses, IR, ¹H NMR, MS and UV-Vis spectroscopy. Alkali metal interactions of the crown ethers on the zinc phthalocyaninato (6) are shown to form intermolecular adduct. The electrochemical properties of ZnPc were investigated by using cyclic voltammetry and controlled potential coulometry.

Original language	English
Pages (from-to)	151-157
Number of pages	7
Journal	Dyes and Pigments
Volume	68
Issue number	2-3
DOIs	https://doi.org/10.1016/j.dyepig.2005.01.018
Publication status	Published - 2006

Keywords

Alkali metal extraction
Crown ether
Electrochemistry
Phthalocyanine complexes

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10.1016/j.dyepig.2005.01.018

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title = "Synthesis and solution properties of phthalocyanines substituted with four crown ethers",

abstract = "Metal-free and metal phthalocyanines (M = Ni, Zn, Co) substituted with four benzo-15-crown-5 units through oxy-bridges have been synthesized from a new phthalonitrile derivative, 1-\{[(benzo-15-crown-5)-4′-yl]oxy\}phthalonitrile (3). The newly prepared compounds have been characterized by elemental analyses, IR, 1H NMR, MS and UV-Vis spectroscopy. Alkali metal interactions of the crown ethers on the zinc phthalocyaninato (6) are shown to form intermolecular adduct. The electrochemical properties of ZnPc were investigated by using cyclic voltammetry and controlled potential coulometry.",

keywords = "Alkali metal extraction, Crown ether, Electrochemistry, Phthalocyanine complexes",

author = "Esin Hamuryudan",

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doi = "10.1016/j.dyepig.2005.01.018",

language = "English",

volume = "68",

pages = "151--157",

journal = "Dyes and Pigments",

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T1 - Synthesis and solution properties of phthalocyanines substituted with four crown ethers

AU - Hamuryudan, Esin

PY - 2006

Y1 - 2006

N2 - Metal-free and metal phthalocyanines (M = Ni, Zn, Co) substituted with four benzo-15-crown-5 units through oxy-bridges have been synthesized from a new phthalonitrile derivative, 1-{[(benzo-15-crown-5)-4′-yl]oxy}phthalonitrile (3). The newly prepared compounds have been characterized by elemental analyses, IR, 1H NMR, MS and UV-Vis spectroscopy. Alkali metal interactions of the crown ethers on the zinc phthalocyaninato (6) are shown to form intermolecular adduct. The electrochemical properties of ZnPc were investigated by using cyclic voltammetry and controlled potential coulometry.

AB - Metal-free and metal phthalocyanines (M = Ni, Zn, Co) substituted with four benzo-15-crown-5 units through oxy-bridges have been synthesized from a new phthalonitrile derivative, 1-{[(benzo-15-crown-5)-4′-yl]oxy}phthalonitrile (3). The newly prepared compounds have been characterized by elemental analyses, IR, 1H NMR, MS and UV-Vis spectroscopy. Alkali metal interactions of the crown ethers on the zinc phthalocyaninato (6) are shown to form intermolecular adduct. The electrochemical properties of ZnPc were investigated by using cyclic voltammetry and controlled potential coulometry.

KW - Alkali metal extraction

KW - Crown ether

KW - Electrochemistry

KW - Phthalocyanine complexes

UR - https://www.scopus.com/pages/publications/20544459729

U2 - 10.1016/j.dyepig.2005.01.018

DO - 10.1016/j.dyepig.2005.01.018

M3 - Article

AN - SCOPUS:20544459729

SN - 0143-7208

VL - 68

SP - 151

EP - 157

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 2-3

ER -

Synthesis and solution properties of phthalocyanines substituted with four crown ethers

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Keywords

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