Synthesis and reactions of polymers with photoactive terminal groups-4. the use of oxocarbenium polymerization for the synthesis of poly(α-methylstyrene) with N-acyl dibenz[b,f]azepine terminal units

Yusuf Yagci; Metin Hayri Acar; Anthony Ledwith

doi:10.1016/0014-3057(92)90073-B

Synthesis and reactions of polymers with photoactive terminal groups-4. the use of oxocarbenium polymerization for the synthesis of poly(α-methylstyrene) with N-acyl dibenz[b,f]azepine terminal units

Yusuf Yagci^*, Metin Hayri Acar, Anthony Ledwith

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

N-chlorocarbonyl dibenz[b,f]azepine in conjunction with AgSbF₆ initiated the cationic polymerization of α-methylstyrene in methylene chloride. Polymer samples obtained this way contained terminal dibenzazepine units. Chain extension occurred upon irradiating these polymers with u.v. in benzene solution containing benzophenone or benzil, via cyclobutane formation.

Original language	English
Pages (from-to)	717-720
Number of pages	4
Journal	European Polymer Journal
Volume	28
Issue number	7
DOIs	https://doi.org/10.1016/0014-3057(92)90073-B
Publication status	Published - Jul 1992

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10.1016/0014-3057(92)90073-B

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title = "Synthesis and reactions of polymers with photoactive terminal groups-4. the use of oxocarbenium polymerization for the synthesis of poly(α-methylstyrene) with N-acyl dibenz[b,f]azepine terminal units",

abstract = "N-chlorocarbonyl dibenz[b,f]azepine in conjunction with AgSbF6 initiated the cationic polymerization of α-methylstyrene in methylene chloride. Polymer samples obtained this way contained terminal dibenzazepine units. Chain extension occurred upon irradiating these polymers with u.v. in benzene solution containing benzophenone or benzil, via cyclobutane formation.",

author = "Yusuf Yagci and Acar, {Metin Hayri} and Anthony Ledwith",

year = "1992",

month = jul,

doi = "10.1016/0014-3057(92)90073-B",

language = "English",

volume = "28",

pages = "717--720",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd",

number = "7",

}

Synthesis and reactions of polymers with photoactive terminal groups-4. the use of oxocarbenium polymerization for the synthesis of poly(α-methylstyrene) with N-acyl dibenz[b,f]azepine terminal units. / Yagci, Yusuf; Acar, Metin Hayri; Ledwith, Anthony.
In: European Polymer Journal, Vol. 28, No. 7, 07.1992, p. 717-720.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and reactions of polymers with photoactive terminal groups-4. the use of oxocarbenium polymerization for the synthesis of poly(α-methylstyrene) with N-acyl dibenz[b,f]azepine terminal units

AU - Yagci, Yusuf

AU - Acar, Metin Hayri

AU - Ledwith, Anthony

PY - 1992/7

Y1 - 1992/7

N2 - N-chlorocarbonyl dibenz[b,f]azepine in conjunction with AgSbF6 initiated the cationic polymerization of α-methylstyrene in methylene chloride. Polymer samples obtained this way contained terminal dibenzazepine units. Chain extension occurred upon irradiating these polymers with u.v. in benzene solution containing benzophenone or benzil, via cyclobutane formation.

AB - N-chlorocarbonyl dibenz[b,f]azepine in conjunction with AgSbF6 initiated the cationic polymerization of α-methylstyrene in methylene chloride. Polymer samples obtained this way contained terminal dibenzazepine units. Chain extension occurred upon irradiating these polymers with u.v. in benzene solution containing benzophenone or benzil, via cyclobutane formation.

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U2 - 10.1016/0014-3057(92)90073-B

DO - 10.1016/0014-3057(92)90073-B

M3 - Article

AN - SCOPUS:0026886689

SN - 0014-3057

VL - 28

SP - 717

EP - 720

JO - European Polymer Journal

JF - European Polymer Journal

IS - 7

ER -

Synthesis and reactions of polymers with photoactive terminal groups-4. the use of oxocarbenium polymerization for the synthesis of poly(α-methylstyrene) with N-acyl dibenz[b,f]azepine terminal units

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