Synthesis and electrochemical polymerization of N-ethylcarbazole-bis-3,4- etyhlenedioxythiophene-N-ethylcarbazole comonomer

A. S. Sarac; E. Farlak; E. Sezer

doi:10.1002/app.25114

Synthesis and electrochemical polymerization of N-ethylcarbazole-bis-3,4- etyhlenedioxythiophene-N-ethylcarbazole comonomer

A. S. Sarac^*, E. Farlak, E. Sezer

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A new comonomer ECz-BEDOT-ECz (EBEE) [ECz: N-ethylcarbazole-BEDOT:2, 2′-bis(3,4-ethyhlenedioxy) thiophene] has been synthesized, characterized, and electropolymerized on Pt and carbon fiber microelectrodes (CFME). The ECz side group of the comonomer plays an important role in determining its physical properties PEBEE and it resembles the behavior of corresponding homopolymer (PECz). PBEDOT was increased by the incorporation of ECz monomer into structure. The environmental stability of PBEDOT was increased by incorporating the ECz unit into the structure. The new comonomer seems prefer to be electrodeposited onto CFME as opposed to Pt.

Original language	English
Pages (from-to)	795-801
Number of pages	7
Journal	Journal of Applied Polymer Science
Volume	103
Issue number	2
DOIs	https://doi.org/10.1002/app.25114
Publication status	Published - 15 Jan 2007

Keywords

Carbon fiber and Pt electrodes
ECZ-BEDOT-ECz comonomer
Electropolymerization

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title = "Synthesis and electrochemical polymerization of N-ethylcarbazole-bis-3,4- etyhlenedioxythiophene-N-ethylcarbazole comonomer",

abstract = "A new comonomer ECz-BEDOT-ECz (EBEE) [ECz: N-ethylcarbazole-BEDOT:2, 2′-bis(3,4-ethyhlenedioxy) thiophene] has been synthesized, characterized, and electropolymerized on Pt and carbon fiber microelectrodes (CFME). The ECz side group of the comonomer plays an important role in determining its physical properties PEBEE and it resembles the behavior of corresponding homopolymer (PECz). PBEDOT was increased by the incorporation of ECz monomer into structure. The environmental stability of PBEDOT was increased by incorporating the ECz unit into the structure. The new comonomer seems prefer to be electrodeposited onto CFME as opposed to Pt.",

keywords = "Carbon fiber and Pt electrodes, ECZ-BEDOT-ECz comonomer, Electropolymerization",

author = "Sarac, {A. S.} and E. Farlak and E. Sezer",

year = "2007",

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T1 - Synthesis and electrochemical polymerization of N-ethylcarbazole-bis-3,4- etyhlenedioxythiophene-N-ethylcarbazole comonomer

AU - Sarac, A. S.

AU - Farlak, E.

AU - Sezer, E.

PY - 2007/1/15

Y1 - 2007/1/15

N2 - A new comonomer ECz-BEDOT-ECz (EBEE) [ECz: N-ethylcarbazole-BEDOT:2, 2′-bis(3,4-ethyhlenedioxy) thiophene] has been synthesized, characterized, and electropolymerized on Pt and carbon fiber microelectrodes (CFME). The ECz side group of the comonomer plays an important role in determining its physical properties PEBEE and it resembles the behavior of corresponding homopolymer (PECz). PBEDOT was increased by the incorporation of ECz monomer into structure. The environmental stability of PBEDOT was increased by incorporating the ECz unit into the structure. The new comonomer seems prefer to be electrodeposited onto CFME as opposed to Pt.

AB - A new comonomer ECz-BEDOT-ECz (EBEE) [ECz: N-ethylcarbazole-BEDOT:2, 2′-bis(3,4-ethyhlenedioxy) thiophene] has been synthesized, characterized, and electropolymerized on Pt and carbon fiber microelectrodes (CFME). The ECz side group of the comonomer plays an important role in determining its physical properties PEBEE and it resembles the behavior of corresponding homopolymer (PECz). PBEDOT was increased by the incorporation of ECz monomer into structure. The environmental stability of PBEDOT was increased by incorporating the ECz unit into the structure. The new comonomer seems prefer to be electrodeposited onto CFME as opposed to Pt.

KW - Carbon fiber and Pt electrodes

KW - ECZ-BEDOT-ECz comonomer

KW - Electropolymerization

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U2 - 10.1002/app.25114

DO - 10.1002/app.25114

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JF - Journal of Applied Polymer Science

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Synthesis and electrochemical polymerization of N-ethylcarbazole-bis-3,4- etyhlenedioxythiophene-N-ethylcarbazole comonomer

Abstract

Keywords

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