Synthesis and complexation of a new vic-dioxime ligand

Esin Hamuryudan; Zehra A. Bayir; Özer Bekaroǧlu

doi:10.1007/PL00010303

Synthesis and complexation of a new vic-dioxime ligand

Esin Hamuryudan, Zehra A. Bayir, Özer Bekaroǧlu^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A new vic-dioxime ligand, N,N′-bis-(8-salicylideneimino-1-naphthyl)-diaminoglyoxime, has been synthesized from anti-dichloroglyoxime and 1-amino-8-salicylideneiminonaphthalene which has been prepared via the condensation product of 1,8-diaminonaphthalene and salicylaldehyde. The vic-dioxime ligand forms trinuclear complexes with Cu(II), Ni(II), Co(II), and Pd(II). The uranyl complex of this ligand has a 2:1 metal-ligand ratio and a binuclear structure with μ-hydroxo bridges.

Original language	English
Pages (from-to)	175-180
Number of pages	6
Journal	Monatshefte fur Chemie
Volume	131
Issue number	2
DOIs	https://doi.org/10.1007/PL00010303
Publication status	Published - 2000

Keywords

Complexation
Schiff base
Vic-dioxime

Access to Document

10.1007/PL00010303

Cite this

@article{7e8c89f6bd294e8ca4e73d4988d4784c,

title = "Synthesis and complexation of a new vic-dioxime ligand",

abstract = "A new vic-dioxime ligand, N,N′-bis-(8-salicylideneimino-1-naphthyl)-diaminoglyoxime, has been synthesized from anti-dichloroglyoxime and 1-amino-8-salicylideneiminonaphthalene which has been prepared via the condensation product of 1,8-diaminonaphthalene and salicylaldehyde. The vic-dioxime ligand forms trinuclear complexes with Cu(II), Ni(II), Co(II), and Pd(II). The uranyl complex of this ligand has a 2:1 metal-ligand ratio and a binuclear structure with μ-hydroxo bridges.",

keywords = "Complexation, Schiff base, Vic-dioxime",

author = "Esin Hamuryudan and Bayir, {Zehra A.} and {\"O}zer Bekaroǧlu",

year = "2000",

doi = "10.1007/PL00010303",

language = "English",

volume = "131",

pages = "175--180",

journal = "Monatshefte fur Chemie",

issn = "0026-9247",

publisher = "Springer-Verlag Wien",

number = "2",

}

TY - JOUR

T1 - Synthesis and complexation of a new vic-dioxime ligand

AU - Hamuryudan, Esin

AU - Bayir, Zehra A.

AU - Bekaroǧlu, Özer

PY - 2000

Y1 - 2000

N2 - A new vic-dioxime ligand, N,N′-bis-(8-salicylideneimino-1-naphthyl)-diaminoglyoxime, has been synthesized from anti-dichloroglyoxime and 1-amino-8-salicylideneiminonaphthalene which has been prepared via the condensation product of 1,8-diaminonaphthalene and salicylaldehyde. The vic-dioxime ligand forms trinuclear complexes with Cu(II), Ni(II), Co(II), and Pd(II). The uranyl complex of this ligand has a 2:1 metal-ligand ratio and a binuclear structure with μ-hydroxo bridges.

AB - A new vic-dioxime ligand, N,N′-bis-(8-salicylideneimino-1-naphthyl)-diaminoglyoxime, has been synthesized from anti-dichloroglyoxime and 1-amino-8-salicylideneiminonaphthalene which has been prepared via the condensation product of 1,8-diaminonaphthalene and salicylaldehyde. The vic-dioxime ligand forms trinuclear complexes with Cu(II), Ni(II), Co(II), and Pd(II). The uranyl complex of this ligand has a 2:1 metal-ligand ratio and a binuclear structure with μ-hydroxo bridges.

KW - Complexation

KW - Schiff base

KW - Vic-dioxime

UR - http://www.scopus.com/inward/record.url?scp=0034383643&partnerID=8YFLogxK

U2 - 10.1007/PL00010303

DO - 10.1007/PL00010303

M3 - Article

AN - SCOPUS:0034383643

SN - 0026-9247

VL - 131

SP - 175

EP - 180

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 2

ER -

Synthesis and complexation of a new vic-dioxime ligand

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this