Synthesis and characterization of thermally curable polyacetylenes by polymerization of propargyl benzoxazine using rhodium catalyst

Baris Kiskan; Yusuf Yagci

doi:10.1016/j.polymer.2008.03.031

Synthesis and characterization of thermally curable polyacetylenes by polymerization of propargyl benzoxazine using rhodium catalyst

Baris Kiskan, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

A novel acetylene monomer containing benzoxazine group was synthesized and polymerized with [(norbornadiene)rhodium(I) chloride]₂ ([(nbd)RhCl]₂) to give the corresponding polymer. The effect of triethylamine as co-catalyst in the polymerization was investigated. The spectral and thermal analyses confirmed the presence of benzoxazine functionality in the resulting polymer. It is shown that polyacetylene containing benzoxazine side groups undergoes irreversible cis-trans isomerization and thermally activated curing in the absence of any catalyst forming polyacetylene thermoset with high thermal stability.

Original language	English
Pages (from-to)	2455-2460
Number of pages	6
Journal	Polymer
Volume	49
Issue number	10
DOIs	https://doi.org/10.1016/j.polymer.2008.03.031
Publication status	Published - 13 May 2008

Keywords

Polyacetylene
Polybenzoxazine
Thermal curing

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10.1016/j.polymer.2008.03.031

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title = "Synthesis and characterization of thermally curable polyacetylenes by polymerization of propargyl benzoxazine using rhodium catalyst",

abstract = "A novel acetylene monomer containing benzoxazine group was synthesized and polymerized with [(norbornadiene)rhodium(I) chloride]2 ([(nbd)RhCl]2) to give the corresponding polymer. The effect of triethylamine as co-catalyst in the polymerization was investigated. The spectral and thermal analyses confirmed the presence of benzoxazine functionality in the resulting polymer. It is shown that polyacetylene containing benzoxazine side groups undergoes irreversible cis-trans isomerization and thermally activated curing in the absence of any catalyst forming polyacetylene thermoset with high thermal stability.",

keywords = "Polyacetylene, Polybenzoxazine, Thermal curing",

author = "Baris Kiskan and Yusuf Yagci",

year = "2008",

month = may,

day = "13",

doi = "10.1016/j.polymer.2008.03.031",

language = "English",

volume = "49",

pages = "2455--2460",

journal = "Polymer",

issn = "0032-3861",

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TY - JOUR

T1 - Synthesis and characterization of thermally curable polyacetylenes by polymerization of propargyl benzoxazine using rhodium catalyst

AU - Kiskan, Baris

AU - Yagci, Yusuf

PY - 2008/5/13

Y1 - 2008/5/13

N2 - A novel acetylene monomer containing benzoxazine group was synthesized and polymerized with [(norbornadiene)rhodium(I) chloride]2 ([(nbd)RhCl]2) to give the corresponding polymer. The effect of triethylamine as co-catalyst in the polymerization was investigated. The spectral and thermal analyses confirmed the presence of benzoxazine functionality in the resulting polymer. It is shown that polyacetylene containing benzoxazine side groups undergoes irreversible cis-trans isomerization and thermally activated curing in the absence of any catalyst forming polyacetylene thermoset with high thermal stability.

AB - A novel acetylene monomer containing benzoxazine group was synthesized and polymerized with [(norbornadiene)rhodium(I) chloride]2 ([(nbd)RhCl]2) to give the corresponding polymer. The effect of triethylamine as co-catalyst in the polymerization was investigated. The spectral and thermal analyses confirmed the presence of benzoxazine functionality in the resulting polymer. It is shown that polyacetylene containing benzoxazine side groups undergoes irreversible cis-trans isomerization and thermally activated curing in the absence of any catalyst forming polyacetylene thermoset with high thermal stability.

KW - Polyacetylene

KW - Polybenzoxazine

KW - Thermal curing

UR - http://www.scopus.com/inward/record.url?scp=43049138026&partnerID=8YFLogxK

U2 - 10.1016/j.polymer.2008.03.031

DO - 10.1016/j.polymer.2008.03.031

M3 - Article

AN - SCOPUS:43049138026

SN - 0032-3861

VL - 49

SP - 2455

EP - 2460

JO - Polymer

JF - Polymer

IS - 10

ER -

Synthesis and characterization of thermally curable polyacetylenes by polymerization of propargyl benzoxazine using rhodium catalyst

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Keywords

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