Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, Mn(CO) 3Cp] with salicylaldehyde methanesulfonylhydrazone

S. Sert; O. S. Şentürk; Ü Özdemir; N. Karacan; F. Ugur

doi:10.1080/00958970410001666170

Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)₆ (M = Cr, Mo, W), Re(CO)₅Br, Mn(CO) ₃Cp] with salicylaldehyde methanesulfonylhydrazone

S. Sert
, O. S. Şentürk^*
, Ü Özdemir
, N. Karacan
, F. Ugur

^*Corresponding author for this work

Ege University
National Research Council of Canada
Gazi University

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Five new complexes, [M(CO)₅(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)₄Br(salmsh)], 4, and [Mn(CO)₃ (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, E1 mass spectrometry, FT-IR and ¹H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

Original language	English
Pages (from-to)	183-188
Number of pages	6
Journal	Journal of Coordination Chemistry
Volume	57
Issue number	3
DOIs	https://doi.org/10.1080/00958970410001666170
Publication status	Published - 15 Feb 2004
Externally published	Yes

Funding

We thank BP (Turkey) for the provision of photochemical apparatus and the Research Foundation of Ege and Gazi University for funds. We thank TUBITAK_ for allocation of time for NMR, mass spectra and elemental analyses.

Funders
Research Foundation of Ege and Gazi University
BP

Keywords

Metal carbonyls
Methanesulfonylhydrazone
Salicylaldehyde
Sulfonylhydrazone

Access to Document

10.1080/00958970410001666170

Cite this

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title = "Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, Mn(CO) 3Cp] with salicylaldehyde methanesulfonylhydrazone",

abstract = "Five new complexes, [M(CO)5(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)4Br(salmsh)], 4, and [Mn(CO)3 (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, E1 mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.",

keywords = "Metal carbonyls, Methanesulfonylhydrazone, Salicylaldehyde, Sulfonylhydrazone",

author = "S. Sert and {\c S}ent{\"u}rk, \{O. S.\} and {\"U} {\"O}zdemir and N. Karacan and F. Ugur",

year = "2004",

month = feb,

day = "15",

doi = "10.1080/00958970410001666170",

language = "English",

volume = "57",

pages = "183--188",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "3",

}

Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)₆ (M = Cr, Mo, W), Re(CO)₅Br, Mn(CO) ₃Cp] with salicylaldehyde methanesulfonylhydrazone. / Sert, S.; Şentürk, O. S.; Özdemir, Ü et al.
In: Journal of Coordination Chemistry, Vol. 57, No. 3, 15.02.2004, p. 183-188.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, Mn(CO) 3Cp] with salicylaldehyde methanesulfonylhydrazone

AU - Sert, S.

AU - Şentürk, O. S.

AU - Özdemir, Ü

AU - Karacan, N.

AU - Ugur, F.

PY - 2004/2/15

Y1 - 2004/2/15

N2 - Five new complexes, [M(CO)5(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)4Br(salmsh)], 4, and [Mn(CO)3 (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, E1 mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

AB - Five new complexes, [M(CO)5(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)4Br(salmsh)], 4, and [Mn(CO)3 (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, E1 mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

KW - Metal carbonyls

KW - Methanesulfonylhydrazone

KW - Salicylaldehyde

KW - Sulfonylhydrazone

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DO - 10.1080/00958970410001666170

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