Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

Ozan Sanli Şentürk; Ümmühan Özdemir; Sema Sert; Nurcan Karacan; Fadime Uǧur

doi:10.1016/S1387-7003(03)00152-7

Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

Ozan Sanli Şentürk^*
, Ümmühan Özdemir
, Sema Sert
, Nurcan Karacan
, Fadime Uǧur

^*Corresponding author for this work

Ege University
National Research Council of Canada
Gazi University

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Five new complexes, [M(CO)₅(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)₄ Br(apesh)] (4) and [Mn(CO)₃(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)₆] (M = Cr, Mo, W), [Re(CO)₅ Br], and [Mn(CO)₃ Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, ¹H NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5).

Original language	English
Pages (from-to)	926-929
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	7
DOIs	https://doi.org/10.1016/S1387-7003(03)00152-7
Publication status	Published - 1 Jul 2003
Externally published	Yes

Funding

We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. This research was also supported by Gazi University Research Found under Project No 05-98/24. We thank TUBİTAK for allocation of time at the NMR, Mass Spectra and Elemental Analyses.

Funders	Funder number
Gazi University Research Found	05-98/24

Keywords

2-Hydroxyacetophenone ethanesulfonylhydrazone
Metal carbonyls
Photosubstituton

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10.1016/S1387-7003(03)00152-7

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title = "Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone",

abstract = "Five new complexes, [M(CO)5(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4 Br(apesh)] (4) and [Mn(CO)3(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5 Br], and [Mn(CO)3 Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5).",

keywords = "2-Hydroxyacetophenone ethanesulfonylhydrazone, Metal carbonyls, Photosubstituton",

author = "{\c S}ent{\"u}rk, \{Ozan Sanli\} and {\"U}mm{\"u}han {\"O}zdemir and Sema Sert and Nurcan Karacan and Fadime Uǧur",

year = "2003",

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doi = "10.1016/S1387-7003(03)00152-7",

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T1 - Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

AU - Şentürk, Ozan Sanli

AU - Özdemir, Ümmühan

AU - Sert, Sema

AU - Karacan, Nurcan

AU - Uǧur, Fadime

PY - 2003/7/1

Y1 - 2003/7/1

N2 - Five new complexes, [M(CO)5(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4 Br(apesh)] (4) and [Mn(CO)3(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5 Br], and [Mn(CO)3 Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5).

AB - Five new complexes, [M(CO)5(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4 Br(apesh)] (4) and [Mn(CO)3(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5 Br], and [Mn(CO)3 Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5).

KW - 2-Hydroxyacetophenone ethanesulfonylhydrazone

KW - Metal carbonyls

KW - Photosubstituton

UR - https://www.scopus.com/pages/publications/0038038004

U2 - 10.1016/S1387-7003(03)00152-7

DO - 10.1016/S1387-7003(03)00152-7

M3 - Article

AN - SCOPUS:0038038004

SN - 1387-7003

VL - 6

SP - 926

EP - 929

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

Abstract

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Keywords

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