Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines

Z. Altuntaş Bayir; E. Hamuryudan; A. G. Gürek; O. Bekaroǧlu

doi:10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0

Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines

Z. Altuntaş Bayir
, E. Hamuryudan
, A. G. Gürek
, O. Bekaroǧlu^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl₂, CoCl₂ or Zn(O₂CMe)₂] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.

Original language	English
Pages (from-to)	349-353
Number of pages	5
Journal	Journal of Porphyrins and Phthalocyanines
Volume	1
Issue number	4
DOIs	https://doi.org/10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0
Publication status	Published - Oct 1997

Keywords

Electrical conductivity
Pentanuclear complex
Phthalocyanine
Thiaethers

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10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0

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title = "Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines",

abstract = "The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl2, CoCl2 or Zn(O2CMe)2] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.",

keywords = "Electrical conductivity, Pentanuclear complex, Phthalocyanine, Thiaethers",

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doi = "10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0",

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T1 - Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines

AU - Altuntaş Bayir, Z.

AU - Hamuryudan, E.

AU - Gürek, A. G.

AU - Bekaroǧlu, O.

PY - 1997/10

Y1 - 1997/10

N2 - The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl2, CoCl2 or Zn(O2CMe)2] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.

AB - The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl2, CoCl2 or Zn(O2CMe)2] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.

KW - Electrical conductivity

KW - Pentanuclear complex

KW - Phthalocyanine

KW - Thiaethers

UR - https://www.scopus.com/pages/publications/0003099559

U2 - 10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0

DO - 10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0

M3 - Article

AN - SCOPUS:0003099559

SN - 1088-4246

VL - 1

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JO - Journal of Porphyrins and Phthalocyanines

JF - Journal of Porphyrins and Phthalocyanines

IS - 4

ER -

Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines

Abstract

Keywords

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