TY - JOUR
T1 - Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines
AU - Altuntaş Bayir, Z.
AU - Hamuryudan, E.
AU - Gürek, A. G.
AU - Bekaroǧlu, O.
PY - 1997/10
Y1 - 1997/10
N2 - The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl2, CoCl2 or Zn(O2CMe)2] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.
AB - The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl2, CoCl2 or Zn(O2CMe)2] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.
KW - Electrical conductivity
KW - Pentanuclear complex
KW - Phthalocyanine
KW - Thiaethers
UR - http://www.scopus.com/inward/record.url?scp=0003099559&partnerID=8YFLogxK
U2 - 10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0
DO - 10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0
M3 - Article
AN - SCOPUS:0003099559
SN - 1088-4246
VL - 1
SP - 349
EP - 353
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
IS - 4
ER -