Synthesis and characterization of novel phthalocyanines with four 16-membered diazadithia macrocycles

Iismail Yilmaz; Özer Bekarogîu

doi:10.1002/cber.19961290815

Synthesis and characterization of novel phthalocyanines with four 16-membered diazadithia macrocycles

Iismail Yilmaz^*, Özer Bekarogîu

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

Metal phthalocyanines (M = Cu, Ni, Co) 3-5 bearing four lo-membered diazadithia macrocycles at the peripheral positions were prepared. Detosylation with concentrated sulfuric acid afforded products containing both sulfonated groups on the aromatic rings of the macrocyclic substituants which are excellently soluble in water and donor sites for binding four Cu^II ions to give a pentanuclear complex.

Original language	English
Pages (from-to)	967-971
Number of pages	5
Journal	Chemische Berichte
Volume	129
Issue number	8
DOIs	https://doi.org/10.1002/cber.19961290815
Publication status	Published - 1996

Keywords

Diazadithiamacrocycles
Pentanuclear complex
Phthalocyanines
Sulphonated

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10.1002/cber.19961290815

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title = "Synthesis and characterization of novel phthalocyanines with four 16-membered diazadithia macrocycles",

abstract = "Metal phthalocyanines (M = Cu, Ni, Co) 3-5 bearing four lo-membered diazadithia macrocycles at the peripheral positions were prepared. Detosylation with concentrated sulfuric acid afforded products containing both sulfonated groups on the aromatic rings of the macrocyclic substituants which are excellently soluble in water and donor sites for binding four CuII ions to give a pentanuclear complex.",

keywords = "Diazadithiamacrocycles, Pentanuclear complex, Phthalocyanines, Sulphonated",

author = "Iismail Yilmaz and {\"O}zer Bekarog{\^i}u",

year = "1996",

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pages = "967--971",

journal = "Chemische Berichte",

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T1 - Synthesis and characterization of novel phthalocyanines with four 16-membered diazadithia macrocycles

AU - Yilmaz, Iismail

AU - Bekarogîu, Özer

PY - 1996

Y1 - 1996

N2 - Metal phthalocyanines (M = Cu, Ni, Co) 3-5 bearing four lo-membered diazadithia macrocycles at the peripheral positions were prepared. Detosylation with concentrated sulfuric acid afforded products containing both sulfonated groups on the aromatic rings of the macrocyclic substituants which are excellently soluble in water and donor sites for binding four CuII ions to give a pentanuclear complex.

AB - Metal phthalocyanines (M = Cu, Ni, Co) 3-5 bearing four lo-membered diazadithia macrocycles at the peripheral positions were prepared. Detosylation with concentrated sulfuric acid afforded products containing both sulfonated groups on the aromatic rings of the macrocyclic substituants which are excellently soluble in water and donor sites for binding four CuII ions to give a pentanuclear complex.

KW - Diazadithiamacrocycles

KW - Pentanuclear complex

KW - Phthalocyanines

KW - Sulphonated

UR - http://www.scopus.com/inward/record.url?scp=0000229842&partnerID=8YFLogxK

U2 - 10.1002/cber.19961290815

DO - 10.1002/cber.19961290815

M3 - Article

AN - SCOPUS:0000229842

SN - 0009-2940

VL - 129

SP - 967

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JO - Chemische Berichte

JF - Chemische Berichte

IS - 8

ER -

Synthesis and characterization of novel phthalocyanines with four 16-membered diazadithia macrocycles

Abstract

Keywords

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