TY - JOUR
T1 - Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy-substituted metallophthalocyanines
AU - Zengin, Hilal
AU - Yenilmez, Hacer Yasemin
AU - Kalkan Burat, Ayfer
AU - Altuntaş Bayir, Zehra
N1 - Publisher Copyright:
© TÜBITAK.
PY - 2014
Y1 - 2014
N2 - The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and copper) bearing four 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, 1H NMR, FT-IR, and UV-Vis spectral data.
AB - The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and copper) bearing four 2-{[2-(dimethylamino)ethyl](methyl)amino} ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, 1H NMR, FT-IR, and UV-Vis spectral data.
KW - 2-{[2(dimethylamino)ethyl]-methylamino} ethanol
KW - Phthalocyanine
KW - Water-soluble
UR - http://www.scopus.com/inward/record.url?scp=84915815195&partnerID=8YFLogxK
U2 - 10.3906/kim-1405-26
DO - 10.3906/kim-1405-26
M3 - Article
AN - SCOPUS:84915815195
SN - 1300-0527
VL - 38
SP - 1094
EP - 1101
JO - Turkish Journal of Chemistry
JF - Turkish Journal of Chemistry
IS - 6
ER -