TY - JOUR
T1 - Synthesis and characterization of new unsymmetrically substituted phthalocyanines
AU - Gürsoy, Süleyman
AU - Bayir, Zehra A.
AU - Hamuryudan, Esin
AU - Bekaroǧlu, Özer
PY - 2000
Y1 - 2000
N2 - Unsymmetric metallophthalocyanines (M = Zn, Co, Ni) carrying alkylthio and acetyl-oxyethylthio groups on peripheral positions were prepared from 4,5-bis-alkylthio-phthalonitrile, 4,5-bis-(acetyloxyethylthio)-phthalonitrile, and the corresponding anhydrous metal salts Zn(CH3COO)2, NiCl2, and CoCl2. The extremely soluble compounds were characterized by their IR, 1H NMR, and UV/Vis spectra. Their long wavelength absorption band was found to be bathochromically shifted; their solubility is superior to that of symmetrical phthalocyanines.
AB - Unsymmetric metallophthalocyanines (M = Zn, Co, Ni) carrying alkylthio and acetyl-oxyethylthio groups on peripheral positions were prepared from 4,5-bis-alkylthio-phthalonitrile, 4,5-bis-(acetyloxyethylthio)-phthalonitrile, and the corresponding anhydrous metal salts Zn(CH3COO)2, NiCl2, and CoCl2. The extremely soluble compounds were characterized by their IR, 1H NMR, and UV/Vis spectra. Their long wavelength absorption band was found to be bathochromically shifted; their solubility is superior to that of symmetrical phthalocyanines.
KW - Alkylthio derivatives
KW - Phthalocyanines
KW - Unsymmetrical substituents
UR - http://www.scopus.com/inward/record.url?scp=0039592575&partnerID=8YFLogxK
U2 - 10.1007/s007060070104
DO - 10.1007/s007060070104
M3 - Article
AN - SCOPUS:0039592575
SN - 0026-9247
VL - 131
SP - 287
EP - 292
JO - Monatshefte fur Chemie
JF - Monatshefte fur Chemie
IS - 3
ER -