Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)

Ozan Sanli Senturk; Sema Sert; Ümmuhan Özdemir

doi:10.1515/znb-2003-1115

Synthesis and Characterization of Metal Carbonyls [M(CO)₆(M = Cr, Mo, W), Re(CO)₅Br, Mn(CO)₃Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)

Ozan Sanli Senturk^*, Sema Sert, Ümmuhan Özdemir

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Five new complexes, M(CO)₅(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)₄Br(nafesh) (4) and Mn(CO)₃ (nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)₆ (M = Cr, Mo, W), Re(CO)₅Br, and Mn(CO)3Cp with 2-hydroxy-1- napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, ¹H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO) ₅(nafesh) (M = Cr, Mo, W) and Re(CO)₄Br(nafesh) and as tridentate ligand in Mn(CO)₃(nafesh).

Original language	English
Pages (from-to)	1124-1127
Number of pages	4
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	58
Issue number	11
DOIs	https://doi.org/10.1515/znb-2003-1115
Publication status	Published - Nov 2003
Externally published	Yes

Funding

This research was supported by Gazi University Research Found under Project No 05-98/24. We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. We thank TUB˙TAK for allocation of time at the NMR, mass spectra and elemental analyses.

Funders	Funder number
Gazi University Research Found	05-98/24

Keywords

2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone
Hydrazone
Metal carbonyls

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10.1515/znb-2003-1115

Cite this

@article{2b342b74e52c4e0cb6d3517107a5a61e,

title = "Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)",

abstract = "Five new complexes, M(CO)5(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)4Br(nafesh) (4) and Mn(CO)3 (nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with 2-hydroxy-1- napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO) 5(nafesh) (M = Cr, Mo, W) and Re(CO)4Br(nafesh) and as tridentate ligand in Mn(CO)3(nafesh).",

keywords = "2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone, Hydrazone, Metal carbonyls",

author = "Senturk, {Ozan Sanli} and Sema Sert and {\"U}mmuhan {\"O}zdemir",

year = "2003",

month = nov,

doi = "10.1515/znb-2003-1115",

language = "English",

volume = "58",

pages = "1124--1127",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "11",

}

Synthesis and Characterization of Metal Carbonyls [M(CO)₆(M = Cr, Mo, W), Re(CO)₅Br, Mn(CO)₃Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh). / Senturk, Ozan Sanli; Sert, Sema; Özdemir, Ümmuhan.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 58, No. 11, 11.2003, p. 1124-1127.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)

AU - Senturk, Ozan Sanli

AU - Sert, Sema

AU - Özdemir, Ümmuhan

PY - 2003/11

Y1 - 2003/11

N2 - Five new complexes, M(CO)5(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)4Br(nafesh) (4) and Mn(CO)3 (nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with 2-hydroxy-1- napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO) 5(nafesh) (M = Cr, Mo, W) and Re(CO)4Br(nafesh) and as tridentate ligand in Mn(CO)3(nafesh).

AB - Five new complexes, M(CO)5(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)4Br(nafesh) (4) and Mn(CO)3 (nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with 2-hydroxy-1- napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO) 5(nafesh) (M = Cr, Mo, W) and Re(CO)4Br(nafesh) and as tridentate ligand in Mn(CO)3(nafesh).

KW - 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone

KW - Hydrazone

KW - Metal carbonyls

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