Synthesis and characterization of metal carbonyl complexes of M(CO) 6 (M = Cr, Mo, and W), Re(CO)5Br, and Mn(CO)3Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)

Ümmühan Özdemir; Nurcan Karacan; Ozan Sanli Şentürk; Sema Sert; Fadime Uǧur

doi:10.1081/SIM-120037527

Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)

Ümmühan Özdemir, Nurcan Karacan, Ozan Sanli Şentürk^*, Sema Sert, Fadime Uǧur

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Ten new complexes, [M(CO)₅(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)₄Br(amsh)] (4a), and [Mn(CO)₂(amsh)Cp] (5a) and [M(CO)₅ (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO) ₄Br(msh)], (4b), and [Mn(CO)₃(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO) ₆] (M = Cr, Mo, and W), [Re(CO)₅Br], and [Mn(CO) ₃Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and ¹H NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).

Original language	English
Pages (from-to)	1057-1067
Number of pages	11
Journal	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume	34
Issue number	6
DOIs	https://doi.org/10.1081/SIM-120037527
Publication status	Published - Jun 2004
Externally published	Yes

Funding

We thank BP (Turkey) for the provision of the photochemical apparatus and the Research Foundation of Ege and Gazi University for funds. We thank TUBİTAK for allocation of time at the NMR, mass spectra and elemental analyses.

Funders	Funder number
Research Foundation of Ege and Gazi University
BP

Keywords

Metal carbonyl complexes
Methanesulfonylhydrazone
Monodentate ligands
Schiff base

Access to Document

10.1081/SIM-120037527

Cite this

Özdemir, Ü., Karacan, N., Şentürk, O. S., Sert, S., & Uǧur, F. (2004). Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh). Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 34(6), 1057-1067. https://doi.org/10.1081/SIM-120037527

Özdemir, Ümmühan ; Karacan, Nurcan ; Şentürk, Ozan Sanli et al. / Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh). In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 2004 ; Vol. 34, No. 6. pp. 1057-1067.

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title = "Synthesis and characterization of metal carbonyl complexes of M(CO) 6 (M = Cr, Mo, and W), Re(CO)5Br, and Mn(CO)3Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)",

abstract = "Ten new complexes, [M(CO)5(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)4Br(amsh)] (4a), and [Mn(CO)2(amsh)Cp] (5a) and [M(CO)5 (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO) 4Br(msh)], (4b), and [Mn(CO)3(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO) 6] (M = Cr, Mo, and W), [Re(CO)5Br], and [Mn(CO) 3Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).",

keywords = "Metal carbonyl complexes, Methanesulfonylhydrazone, Monodentate ligands, Schiff base",

author = "{\"U}mm{\"u}han {\"O}zdemir and Nurcan Karacan and {\c S}ent{\"u}rk, {Ozan Sanli} and Sema Sert and Fadime Uǧur",

year = "2004",

month = jun,

doi = "10.1081/SIM-120037527",

language = "English",

volume = "34",

pages = "1057--1067",

journal = "Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry",

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Özdemir, Ü, Karacan, N, Şentürk, OS, Sert, S & Uǧur, F 2004, 'Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)', Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 34, no. 6, pp. 1057-1067. https://doi.org/10.1081/SIM-120037527

Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh). / Özdemir, Ümmühan; Karacan, Nurcan; Şentürk, Ozan Sanli et al.
In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Vol. 34, No. 6, 06.2004, p. 1057-1067.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterization of metal carbonyl complexes of M(CO) 6 (M = Cr, Mo, and W), Re(CO)5Br, and Mn(CO)3Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)

AU - Özdemir, Ümmühan

AU - Karacan, Nurcan

AU - Şentürk, Ozan Sanli

AU - Sert, Sema

AU - Uǧur, Fadime

PY - 2004/6

Y1 - 2004/6

N2 - Ten new complexes, [M(CO)5(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)4Br(amsh)] (4a), and [Mn(CO)2(amsh)Cp] (5a) and [M(CO)5 (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO) 4Br(msh)], (4b), and [Mn(CO)3(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO) 6] (M = Cr, Mo, and W), [Re(CO)5Br], and [Mn(CO) 3Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).

AB - Ten new complexes, [M(CO)5(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)4Br(amsh)] (4a), and [Mn(CO)2(amsh)Cp] (5a) and [M(CO)5 (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO) 4Br(msh)], (4b), and [Mn(CO)3(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO) 6] (M = Cr, Mo, and W), [Re(CO)5Br], and [Mn(CO) 3Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).

KW - Metal carbonyl complexes

KW - Methanesulfonylhydrazone

KW - Monodentate ligands

KW - Schiff base

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U2 - 10.1081/SIM-120037527

DO - 10.1081/SIM-120037527

M3 - Article

AN - SCOPUS:3242779293

SN - 0094-5714

VL - 34

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EP - 1067

JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

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Özdemir Ü, Karacan N, Şentürk OS, Sert S, Uǧur F. Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh). Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 2004 Jun;34(6):1057-1067. doi: 10.1081/SIM-120037527