Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines

Halit Koçan; Ayfer Kalkan Burat

doi:10.1007/s00706-012-0790-9

Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines

Halit Koçan, Ayfer Kalkan Burat^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, ¹H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.

Original language	English
Pages (from-to)	171-177
Number of pages	7
Journal	Monatshefte fur Chemie
Volume	144
Issue number	2
DOIs	https://doi.org/10.1007/s00706-012-0790-9
Publication status	Published - Feb 2013

Funding

This work was supported by the Research Fund of the Technical University of Istanbul (project no: 33434) and TUBITAK (project no: 110T800).

Funders	Funder number
TUBITAK	110T800
Istanbul Teknik Üniversitesi	33434

Keywords

Aggregation
Isomers
Manganese
Phthalocyanines
Solubility

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title = "Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines",

abstract = "The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, 1H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.",

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N2 - The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, 1H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.

AB - The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, 1H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.

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KW - Isomers

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KW - Phthalocyanines

KW - Solubility

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Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines

Abstract

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Keywords

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